Compilation - Acetonitrile with Heptane (IUPAC SDS Volume 78)
SDS Volume (5198)
Volume 78. Acetonitrile Binary Systems, p None
Original Measurements
Comish, R. E.; Archibald, R. C.; Murphy, E. A.; Evans, H. M.; Ind. Eng. Chem. 26, 397-406 (1934).
Variables:
Temperature: 357 K
Prepared by:
Method/Apparatus/Procedure:
The synthetic method was used. Determinations were made in test tubes, which were heated and allowed to cool slowly in air. Thermometers were roughly calibrated.
Source and Purity of Materials:
- Prepared from sodium cyanide and dimethyl sulfate; the crude product was distilled and successively washed with solid sodium hydroxide and P2O5; carefully fractionated in a 6.09 m column; d(20°C,4°C)=0.782 15.
- Source not specified; commercial high-grade reagent.
Acetonitrile with Heptane
Components:
(1) Acetonitrile,
$\ce{ C2H3N }$;
[75-05-8]
NIST WebBook
(2) Heptane,
$\ce{ C7H16 }$;
[142-82-5]
NIST WebBook
Experimental Values:
The upper critical solution temperature (UCST) was reported to be 84.0°C (357.2 K, compilers).
