Compilation - Acetonitrile with Hexane (IUPAC SDS Volume 78)
SDS Volume (5191)
Volume 78. Acetonitrile Binary Systems, p None
Original Measurements
Nagata, I.; Thermochim. Acta 114, 227 (1987).
Variables:
Room Temp: 298 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The analytical method was used. Each two-phase mixture in a 70 mL equilibrium cell was stirred intensely for 2 h and then was allowed to settle for 2 h at 25.00 °C in a thermostated water bath. Two liquid samples in equilibrium were withdrawn with Hamilton syringes and were analyzed by means of a gas chromatograph and an electronic integrator.
Source and Purity of Materials:
- Source not specified; guaranteed reagent; not purified.
- Source not specified; not purified; GLC did not detect any appreciable impurities.
Estimated Errors:
Ambient temperature: ±0.01 K
Composition: ±0.002 mole fractions.
Components:
- Acetonitrile, $\ce{ C2H3N }$; [75-05-8] NIST WebBook
- Hexane, $\ce{ C6H14 }$; [110-54-3] NIST WebBook
Experimental Data
Mutual solubility of acetonitrile (1) and hexane (2)
| $T$ (°C) | $T$ ($\pu{K}$) | $x_{1}$ | 100w1 |
|---|---|---|---|
| 25.00 | 298.15 | 0.0584 | 2.87 |
| 25.00 | 298.15 | 0.9433 | 88.79 |
