Compilation - Acetonitrile with Butane (IUPAC SDS Volume 78)
SDS Volume (5162)
Volume 78. Acetonitrile Binary Systems, p None
Original Measurements
Warowny, W.; J. Chem. Eng. Data 41, 689 (1996).
Variables:
Room Temp:
319 - 336
$\pu{K}$
Pressure:
0.45 - 0.68
$\pu{MPa}$
Prepared by:
Method/Apparatus/Procedure:
The synthetic method was used. The apparatus, filling procedure, and method of the measurements were described elsewhere [1].
Source and Purity of Materials:
- Source not specified; purity not specified; degassed and dried over molecular sieves.
- Fluka A. G.; purity of 99.9 mole%; used without further purification.
Estimated Errors:
Ambient temperature: ±0.02 K
Pressure: ±0.006 MPa.
References
Components:
- Acetonitrile, $\ce{ C2H3N }$; [75-05-8] NIST WebBook
- Butane, $\ce{ C4H10 }$; [106-97-8] NIST WebBook
Experimental Data
Mutual solubility of acetonitrile (1) and butane (2) at moderate pressure
| $T$ (°C) | $T$ ($\pu{K}$) | $P$ ($\pu{kPa}$) | $x_{1}$ | w1 |
|---|---|---|---|---|
| 46.15 | 319.30 | 449.1 | 0.1312 | 9.64 |
| 54.96 | 328.11 | 563.1 | - | - |
| 54.45 | 328.60 | 570.0 | 0.2229 | 16.85 |
| 55.67 | 329.82 | 586.3 | 0.2422 | 18.42 |
| 60.00 | 333.15 | 636.2 | 0.3167 | 24.66 |
| 62.70 | 335.85 | 677.8 | 0.4858 | 40.02 |
| 62.87 | 336.02 | 680.6 | - | - |
| 63.00 | 336.15 | 682.5 | 0.5338 | 44.71 |
| 63.07 | 336.22 | 683.5 | 0.571 | 48.5 |
| 46.15 | 319.30 | 449.1 | - | - |
| 54.96 | 328.11 | 563.1 | 0.7354 | 66.25 |
| 54.45 | 328.60 | 570.0 | - | - |
| 55.67 | 329.82 | 586.3 | - | - |
| 60.00 | 333.15 | 636.2 | 0.6868 | 60.77 |
| 62.70 | 335.85 | 677.8 | - | - |
| 62.87 | 336.02 | 680.6 | 0.6051 | 51.98 |
| 63.00 | 336.15 | 682.5 | - | - |
| 63.07 | 336.22 | 683.5 | 0.571 | UCST |
