Compilation - Acetonitrile with Triglycerides (IUPAC SDS Volume 78)

SDS Volume (5131)

Volume 78. Acetonitrile Binary Systems, p 1114

Original Measurements

Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Microchem. J. 7, 297-302 (1963).

Variables:

Room Temp: 326 - 462 $\pu{K}$

Prepared by:

V.P. Sazonov

Method/Apparatus/Procedure:

The synthetic method was used. A Reichert microscope, type RCH, equipped with a heating stage was used as described elsewhere [1]. The disappearance and reappearance of the interface between (1) and (2) could be observed without difficulty.

Source and Purity of Materials:
  1. Baker Chemical Co.; reagent No. 9011; $n_{D}^{20}$ = 1.3445, $d_{4}^{20}$ = 0.780.
  2. Monoacid triglycerides obtained from the Hormel Foundation, other triglycerides from Procter & Gamble Co.; purity verified by thin-layer adsorption chromatography.
Estimated Errors:

Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.

References

1 Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Microchem. J. 7, 287-96 (1963).

Components:
  1. Acetonitrile $\ce{ C2H3N }$ [75-05-8]; NIST WebBook
  2. 1,2,3-Tridecanoyloxypropane $\ce{ C33H62O6 }$ [621-71-6]; NIST WebBook
    1,2,3-Tri(cis,cis,cis-9,12,15-octadecatrienoyloxy)propane $\ce{ C57H92O6 }$ [14465-68-0]; NIST WebBook
    1,2,3-Tridodecanoyloxypropane $\ce{ C39H74O6 }$ [538-24-9]; NIST WebBook
    1,2,3-Tri(cis,cis,cis-9,12-octadecadienoyloxy)propane $\ce{ C57H98O6 }$ [537-40-6]; NIST WebBook
    1,2,3-Tri(cis-9-hexadecenoyloxy)propane $\ce{ C51H92O6 }$ [20246-55-3]; NIST WebBook
    1,2,3-Tritetradecanoyloxypropane $\ce{ C45H86O6 }$ [555-45-3]; NIST WebBook
    1,2,3-Tri(cis-9-octadecenoyloxy)propane $\ce{ C57H104O6 }$ [122-32-7]; NIST WebBook
    1,2,3-Tri(cis-6-octadecenoyloxy)propane $\ce{ C57H104O6 }$ [50650-45-8]; NIST WebBook
    1-Hexadecanoyloxy-2,3-di(cis-9-octadecenoyloxy)propane $\ce{ C55H102O6 }$ [27071-84-7]; NIST WebBook
    2-Hexadecanoyloxy-1,3-di(cis-9-octadecenoyloxy)propane $\ce{ C55H102O6 }$ [1716-07-0]; NIST WebBook
    1,2,3-Tri(trans-9-octadecenoyloxy)propane $\ce{ C57H104O6 }$ [537-39-3]; NIST WebBook
    1,2,3-Trihexadecanoyloxypropane $\ce{ C51H98O6 }$ [555-44-2]; NIST WebBook
    1,3-Dihexadecanoyloxy-2-(cis-9-octadecenoyloxy)propane $\ce{ C53H100O6 }$ [28409-94-1]; NIST WebBook
    1-Octadecanoyloxy-2,3-di(cis-9-octadecenoyloxy) propane $\ce{ C57H106O6 }$ [29590-02-1]; NIST WebBook
    2-Octadecanoyloxy-1,3-di(cis-9-octadecenoyloxy) propane $\ce{ C57H106O6 }$ [2410-29-9]; NIST WebBook
    1-Hexadecanoyloxy-2-octadecenoyloxy-3-(cis-9-octadecenoyloxy)propane $\ce{ C55H104O6 }$ [26836-31-7]; NIST WebBook
    1-Hexadecanoyloxy-3-octadecenoyloxy-2-(cis-9-octadecenoyloxy)propane $\ce{ C55H104O6 }$
    1,3-Dioctadecanoyloxy-2-(cis-9-octadecenoyloxy) propane $\ce{ C57H108O6 }$ [28880-75-3]; NIST WebBook
    1,2,3-Tri-11-eicosenoyloxypropane $\ce{ C63H116O6 }$ [115936-00-0]; NIST WebBook
    1,2,3-Trioctadecanoyloxypropane $\ce{ C57H110O6 }$ [555-43-1]; NIST WebBook
    1,2,3-Tri(cis-13-docosenoyloxy)propane $\ce{ C69H128O6 }$ [2752-99-0]; NIST WebBook
    1,2,3-Trieicosanoyloxypropane $\ce{ C63H122O6 }$ [620-64-4]; NIST WebBook
Experimental Data

Upper critical solution temperatures of the binary systems acetonitrile (1) with triglycerides (2)

Triglycerides (x22) $T$ (°C) $T$ ($\pu{K}$)
1,2,3-Tridecanoyloxypropane (link to XML output link to JSON output link to JSON-LD output) 53.0326.2
1,2,3-Tri(cis,cis,cis-9,12,15-octadecatrienoyloxy)propane (link to XML output link to JSON output link to JSON-LD output) 88.0361.2
1,2,3-Tridodecanoyloxypropane (link to XML output link to JSON output link to JSON-LD output) 91.5364.7
1,2,3-Tri(cis,cis,cis-9,12-octadecadienoyloxy)propane (link to XML output link to JSON output link to JSON-LD output) 113.5386.7
1,2,3-Tri(cis-9-hexadecenoyloxy)propane (link to XML output link to JSON output link to JSON-LD output) 114.5387.7
1,2,3-Tritetradecanoyloxypropane (link to XML output link to JSON output link to JSON-LD output) 120.0393.2
1,2,3-Tri(cis-9-octadecenoyloxy)propane (link to XML output link to JSON output link to JSON-LD output) 140.0413.2
1,2,3-Tri(cis-6-octadecenoyloxy)propane (link to XML output link to JSON output link to JSON-LD output) 142.0415.2
1-Hexadecanoyloxy-2,3-di(cis-9-octadecenoyloxy)propane (link to XML output link to JSON output link to JSON-LD output) 142.0415.2
2-Hexadecanoyloxy-1,3-di(cis-9-octadecenoyloxy)propane (link to XML output link to JSON output link to JSON-LD output) 142.0415.2
1,2,3-Tri(trans-9-octadecenoyloxy)propane (link to XML output link to JSON output link to JSON-LD output) 145.0418.2
1,2,3-Trihexadecanoyloxypropane (link to XML output link to JSON output link to JSON-LD output) 145.0418.2
1,3-Dihexadecanoyloxy-2-(cis-9-octadecenoyloxy)propane (link to XML output link to JSON output link to JSON-LD output) 145.5418.7
1-Octadecanoyloxy-2,3-di(cis-9-octadecenoyloxy) propane (link to XML output link to JSON output link to JSON-LD output) 147.5420.7
2-Octadecanoyloxy-1,3-di(cis-9-octadecenoyloxy) propane (link to XML output link to JSON output link to JSON-LD output) 147.5420.7
1-Hexadecanoyloxy-2-octadecenoyloxy-3-(cis-9-octadecenoyloxy)propane (link to XML output link to JSON output link to JSON-LD output) 152.0425.2
1-Hexadecanoyloxy-3-octadecenoyloxy-2-(cis-9-octadecenoyloxy)propane (link to XML output link to JSON output link to JSON-LD output) 152.0425.2
1,3-Dioctadecanoyloxy-2-(cis-9-octadecenoyloxy) propane (link to XML output link to JSON output link to JSON-LD output) 158.0431.2
1,2,3-Tri-11-eicosenoyloxypropane (link to XML output link to JSON output link to JSON-LD output) 160.5433.7
1,2,3-Trioctadecanoyloxypropane (link to XML output link to JSON output link to JSON-LD output) 170.0443.0
1,2,3-Tri(cis-13-docosenoyloxy)propane (link to XML output link to JSON output link to JSON-LD output) 182.0455.2
1,2,3-Trieicosanoyloxypropane (link to XML output link to JSON output link to JSON-LD output) 189.0462.2