SDS Volume (5127)

Volume 78. Acetonitrile Binary Systems, p None

Original Measurements

Ralston, A. W.; Hoerr, C. W.; Pool, W. O.; J. Org. Chem. 8, 473-88 (1943).

Variables:

Room Temp: 283 - 323 $\pu{K}$

Prepared by:

N.V. Sazonov, V.P. Sazonov

Method/Apparatus/Procedure:

The synthetic method was used. The solubilities of (2) in (1) were determined in sealed tubes by the method and apparatus described elsewhere [1,2].

Source and Purity of Materials:

1. Source not specified; best grade reagent; dried and twice distilled.
2. Prepared by heating the dodecanoyl chloride with diphenylamine for two to four hours at 135°C to 145°C; purified by recrystallization; FP = 57°C

Estimated Errors:

Ambient temperature: ±0.2 K.

References

¹ Ralston, A. W.; Hoerr, C. W.; Hoffman, E. J.; J. Am. Chem. Soc. 64, 1516 (1942).
² Hoerr, C. W.; Ralston, A. W., J. Am. Chem. Soc. 64, 2824 (1942).