SDS Volume
Volume 78. Acetonitrile Binary Systems, p 1008
Source Publication
Poppe, G.; Bull. Soc. Chim. Belg. 44, 640-57 (1935).
Conditions:
Room Temp:
324
$\pu{K}$
Pressure:
582 - 9803
Compiler:
Methodology:
The synthetic method was used. Observations were carried out in sealed tubes in the presence of the vapor phase. A Cailletet tube with a Kuenen electromagnetic stirrer was used in the experiments at higher pressure. A thermostating cylinder was also used to control the temperature.
Sample Information:
- Obtained from the Bureau Etalons Physico-Chimiques.
- Obtained from the Bureau Etalons Physico-Chimiques.
Measurement Errors:
Pressure: ±100 kPa.
System Components:
- Acetonitrile, $\ce{ C2H3N }$; [75-05-8] NIST WebBook
- Carbon disulfide, $\ce{ CS2 }$; [75-15-0] NIST WebBook
Experimental Data
The upper critical solution temperature (UCST) was reported to be 50.90°C (324.05 K, compiler). The value of dTc/dP was reported to be 0.0197 K·kPa-1 in the pressure range 582 kPa to 9803 kPa.
