SDS Volume
Volume 78. Acetonitrile Binary Systems, p 1088
Source Publication
Smagowski, H.; Zesz. Nauk. Wydz. Mat., Fiz. Chem., Univ. Gdanski, Chem. 3, 45-53 (1974).
Conditions:
Room Temp: 273 - 308 $\pu{K}$
Compiler:
Methodology:
The titration method was used: 25 mL of [1] and an amount of (2) exceeding the solubility were placed in 50 mL volumetric flasks. The flasks were closed by ground glass stoppers and stored at the required temperature in a thermostat for 45 hours, with intensive stirring every several hours. After this, 5 mL samples of the saturated solution were taken by pipette, diluted to 25 mL with water and titrated against 0.07 0.1 N sodium hydroxide solutions by using phenolphthalein indicator.
Sample Information:
- Source not specified; purity not specified; dried over anhydrous $\ce{K2CO3}$ and repeatedly distilled over $\ce{P2O5}$.
- Source not specified; purity not specified; purified by crystallization from water.
Measurement Errors:
Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
Methodology Citation
1 Timmermans, J.; Physico-Chemical Constants of Pure Organic Compounds (Elsevier, New York, 1950).
System Components:
- Acetonitrile, $\ce{ C2H3N }$; [75-05-8] NIST WebBook
- Nonanedioic acid, $\ce{ C9H16O4 }$; [123-99-9] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | $C_{1}$ (mol/L) | 100w2 | $x_{2}$ |
|---|---|---|---|---|
| 0.0 | 273.2 | 8 x 10-3 | 1.9 x 10-3 | 4.2 x 10-4 |
| 15.0 | 288.2 | 0.010 | 2.4 x 10-3 | 5.2 x 10-4 |
| 25.0 | 298.2 | 0.019 | 4.6 x 10-3 | 1.01 x 10-3 |
| 35.0 | 308.2 | 0.069 | 0.017 | 3.8 x 10-3 |
(a) For these calculations the compiler assumed that the densities of the solutions were those of acetonitrile1 at the specified temperatures.
