SDS Volume
Volume 78. Acetonitrile Binary Systems, p 1077
Source Publication
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Baumann, W. J.; Microchem. J. 11, 306-14 (1966).
Conditions:
Room Temp: 464 - 495 $\pu{K}$
Compiler:
Methodology:
A microscope equipped with a heating stage as in Schmid, et al. [1]. was employed for determining UCST values. No experimental details are given.
Sample Information:
- Baker Chemical Co.; reagent No. 9011.
- Synthesized as in work of Baumann and Mangold [2].
Measurement Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Methodology Citations
1
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).
2
Baumann, W. J.; Mangold, H. K.; J. Org. Chem. 29, 3055 (1964).
System Components:
- Acetonitrile $\ce{ C2H3N }$ [75-05-8]; NIST WebBook
-
1-(Dodecyloxy)-2,3-bis(hexadecyloxy)propane $\ce{ C47H96O3 }$
[6076-43-3];
NIST WebBook
(Z,Z,Z)-1,2,3-Tris(9-octadecenyloxy)propane $\ce{ C57H110O3 }$ [10431-15-9]; NIST WebBook
1-[3-(Dodecyloxy)-2-(hexadecyloxy)propoxy]octadecane $\ce{ C49H100O3 }$ [6068-27-5]; NIST WebBook
1-(Dodecyloxy)-2,3-bis(octadecyloxy)-propane $\ce{ C51H104O3 }$ [5896-48-0]; NIST WebBook
1,2,3-Tris(hexadecyloxy)propane $\ce{ C51H104O3 }$ [6110-59-4]; NIST WebBook
(Z,Z)-1,2-bis(9-Octadecenyloxy)-3-(octadecyloxy)-propane $\ce{ C57H112O3 }$ [10431-14-8]; NIST WebBook
(Z)-1-(9-Octadecenyloxy)-2,3-bis(octadecyloxy)propane $\ce{ C57H114O3 }$ [13166-06-8]; NIST WebBook
Glycerine tristearyl ether $\ce{ C57H116O3 }$ [6076-42-2]; NIST WebBook
Experimental Data
Upper critical solution temperatures of the binary systems acetonitrile (1) with 1,2,3-trialkyl glyceryl ether (2)
| 1,2,3-Trialkyl glyceryl ethers ($\ce{C47H96O3} – $\ce{C57H116O3}$) | $T$ (°C) | $T$ ($\pu{K}$) |
|---|---|---|
1-(Dodecyloxy)-2,3-bis(hexadecyloxy)propane
(
 )
|
191.0 | 464.2 |
|
(Z,Z,Z)-1,2,3-Tris(9-octadecenyloxy)propane
(
)
|
196.5 | 469.7 |
|
1-[3-(Dodecyloxy)-2-(hexadecyloxy)propoxy]octadecane
(
)
|
198.0 | 471.2 |
|
1-(Dodecyloxy)-2,3-bis(octadecyloxy)-propane
(
)
|
204.5 | 477.7 |
|
1,2,3-Tris(hexadecyloxy)propane
(
)
|
204.5 | 477.7 |
|
(Z,Z)-1,2-bis(9-Octadecenyloxy)-3-(octadecyloxy)-propane
(
)
|
206.0 | 479.2 |
|
(Z)-1-(9-Octadecenyloxy)-2,3-bis(octadecyloxy)propane
(
)
|
213.5 | 486.7 |
|
Glycerine tristearyl ether
(
)
|
222.0 | 495.2 |