SDS Volume (5051)
Volume 78. Acetonitrile Binary Systems, p None
Original Measurements
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Baumann, W. J.; Microchem. J. 11, 306-14 (1966).
Variables:
Room Temp: 464 - 495 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
A microscope equipped with a heating stage as in Schmid, et al. [1]. was employed for determining UCST values. No experimental details are given.
Source and Purity of Materials:
- Baker Chemical Co.; reagent No. 9011.
- Synthesized as in work of Baumann and Mangold [2].
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
References
1
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).
2
Baumann, W. J.; Mangold, H. K.; J. Org. Chem. 29, 3055 (1964).
Components:
- Acetonitrile, $\ce{ C2H3N }$; [75-05-8] NIST WebBook
- Glycerol 1-lauryl-2,3-dicetyl ether, $\ce{ C47H96O3 }$; [6076-43-3] NIST WebBook
- 1-[3-(Dodecyloxy)-2-(hexadecyloxy)propoxy]octadecane, $\ce{ C49H100O3 }$; [6068-27-5] NIST WebBook
- 1-(Dodecyloxy)-2,3-bis(octadecyloxy)-propane, $\ce{ C51H104O3 }$; [5896-48-0] NIST WebBook
- Trihexadecyl glycerol, $\ce{ C51H104O3 }$; [6110-59-4] NIST WebBook
- Trioleylglyceryl ether, $\ce{ C57H110O3 }$; [10431-15-9] NIST WebBook
- (Z,Z)-1,2-bis(9-Octadecenyloxy)-3-(octadecyloxy)-propane, $\ce{ C57H112O3 }$; [10431-14-8] NIST WebBook
- 2,3-Dioctadecyloxy-1-cis-9-octadecenyloxy-propane, $\ce{ C57H114O3 }$; [13166-06-8] NIST WebBook
- Glycerine tristearyl ether, $\ce{ C57H116O3 }$; [6076-42-2] NIST WebBook
Experimental Data
Upper critical solution temperatures of the binary systems acetonitrile (1) + 1,2,3-trialkyl glyceryl ether (2)
| $T$ (°C) | $T$ ($\pu{K}$) |
|---|---|
| 191.0 | 464.2 |
| 196.5 | 469.7 |
| 198.0 | 471.2 |
| 204.5 | 477.7 |
| 204.5 | 477.7 |
| 206.0 | 479.2 |
| 213.5 | 486.7 |
| 222.0 | 495.2 |
