SDS Volume
Volume 78. Acetonitrile Binary Systems, p 1076
Source Publication
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Baumann, W. J.; Microchem. J. 11, 306-14 (1966).
Conditions:
Room Temp: 392 - 430 $\pu{K}$
Compiler:
Methodology:
A microscope equipped with a heating stage as in Schmid, et al. [1]. was employed for determining UCST values. No experimental details are given.
Sample Information:
- Baker Chemical Co.; reagent No. 9011.
- Synthesized as in work of Baumann and Mangold [2].
Measurement Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Methodology Citations
1
Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).
2
Baumann, W. J.; Mangold, H. K.; J. Org. Chem. 29, 3055 (1964).
System Components:
- Acetonitrile $\ce{ C2H3N }$ [75-05-8]; NIST WebBook
-
2-(Dodecyloxy)-3-(octadecyloxy)-1-propanol $\ce{ C33H68O3 }$
[6076-36-4];
NIST WebBook
2,3-bis[(Z)-octadec-9-enoxy]propan-1-ol $\ce{ C39H76O3 }$ [6076-41-1]; NIST WebBook
3-(Octadecyloxy)-2-(tetradecyloxy)-1-propanol $\ce{ C35H72O3 }$ [6076-37-5]; NIST WebBook
2,3-Bis(hexadecyloxy)-1-propanol $\ce{ C35H72O3 }$ [6076-35-3]; NIST WebBook
3-(Octadecyloxy)-2-(cis-9-octadecenyloxy)-1-propanol $\ce{ C39H78O3 }$
3-(cis-9-Octadecenyloxy)-2-(octadecyloxy)-1-propanol $\ce{ C39H78O3 }$
3-(Octadecyloxy)-2-(trans-9-octadecenyloxy)-1-propanol $\ce{ C39H78O3 }$
3-(Hexadecyloxy)-2-(octadecyloxy)-1-propanol $\ce{ C37H76O3 }$ [6110-57-2]; NIST WebBook
2-(Hexadecyloxy)-3-(octadecyloxy)-1-propanol $\ce{ C37H76O3 }$ [6110-58-3]; NIST WebBook
2,3-Bis(octadecyloxy)-1-propanol $\ce{ C39H80O3 }$ [6076-38-6]; NIST WebBook
2-(Eicosyloxy)-3-(octadecyloxy)-1-propanol $\ce{ C41H84O3 }$ [6068-26-4]; NIST WebBook
Experimental Data
Upper critical solution temperatures of the binary systems acetonitrile (1) with 1,2-dialkyl glyceryl ethers (2)
| 1,2-Dialkyl glyceryl ethers | $T$ (°C) | $T$ ($\pu{K}$) |
|---|---|---|
2-(Dodecyloxy)-3-(octadecyloxy)-1-propanol
(
 )
|
118.5 | 391.7 |
|
2,3-bis[(Z)-octadec-9-enoxy]propan-1-ol
(
)
|
121.5 | 394.7 |
|
3-(Octadecyloxy)-2-(tetradecyloxy)-1-propanol
(
)
|
129.5 | 402.7 |
|
2,3-Bis(hexadecyloxy)-1-propanol
(
)
|
130.0 | 403.2 |
|
3-(Octadecyloxy)-2-(cis-9-octadecenyloxy)-1-propanol
(
)
|
135.5 | 408.7 |
|
3-(cis-9-Octadecenyloxy)-2-(octadecyloxy)-1-propanol
(
)
|
135.5 | 408.7 |
|
3-(Octadecyloxy)-2-(trans-9-octadecenyloxy)-1-propanol
(
)
|
138.5 | 411.7 |
|
3-(Hexadecyloxy)-2-(octadecyloxy)-1-propanol
(
)
|
140.5 | 413.7 |
|
2-(Hexadecyloxy)-3-(octadecyloxy)-1-propanol
(
)
|
140.5 | 413.7 |
|
2,3-Bis(octadecyloxy)-1-propanol
(
)
|
148.5 | 421.7 |
|
2-(Eicosyloxy)-3-(octadecyloxy)-1-propanol
(
)
|
156.5 | 429.7 |