Components:
(1) Acetonitrile,
C2H3N; [75-05-8]
NIST WebBook
(2) 1,1'-Oxybispentane,
C10H22O; [693-65-2]
NIST WebBook
Original Measurements
Sazonov, V. P.; Gudkina, L. V.; Zh. Prikl. Khim. 47, 2515-8 (1974).
Variables:
Ambient temperature: 298 - 306 K
Prepared by:
Method/Apparatus/Procedure:
The synthetic method was used. No experimental details were reported.
Source and Purity of Materials:
- Soyuzreaktiv, USSR; CP reagent; dried over P2O5 and twice distilled in a laboratory packed column; n(20°C, D) = 1.3440, d(20°C, 4°C) = 0.7828.
- Soyuzreaktiv, USSR; pure grade reagent; dried over CaCl2 and purified by two vacuum distillations over sodium; d(20°C, 4°C) = 0.7838.
Estimated Errors:
Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
Experimental Values:
Mutual solubility of acetonitrile (1) and 1,1'-oxybispentane (2)
| T (°C) | T (K) | w1 | x1 |
|---|---|---|---|
| 24.5 | 297.65 | - | - |
| 28.6 | 301.75 | - | - |
| 29.0 | 302.15 | 24.6 | 5.57 x 10-1 |
| 30.8 | 303.95 | - | - |
| 31.55 | 304.7 | 29.3 | 6.15 x 10-1 |
| 32.4 | 305.55 | - | - |
| 32.65 | 305.8 | 34.7 | 6.72 x 10-1 |
| 32.9 | 306.05 | 39.9 | 7.19 x 10-1 |
| 32.95 | 306.1 | 44.6 | 7.56 x 10-1 |
| 24.5 | 297.65 | 70.1 | 9.00 x 10-1 |
| 28.6 | 301.75 | 64.9 | 8.77 x 10-1 |
| 29.0 | 302.15 | - | - |
| 30.8 | 303.95 | 60.0 | 8.53 x 10-1 |
| 31.55 | 304.7 | - | - |
| 32.4 | 305.55 | 54.6 | 8.23 x 10-1 |
| 32.65 | 305.8 | - | - |
| 32.9 | 306.05 | 50.0 | 7.94 x 10-1 |
| 32.95 | 306.1 | 44.6 | 7.56 x 10-1 |
