SDS Volume

Volume 78. Acetonitrile Binary Systems, p 1072

Source Publication

Garland, F. M.; Hoerr, C. W.; Pool, W. O.; Ralston, A. W.; J. Org. Chem. 8, 344-57 (1943).

Conditions:

Room Temp: 283 - 333 $\pu{K}$

Compiler:

V.P. Sazonov

Methodology:

The synthetic method was used. The solubilities of (2) in (1) were determined in sealed tubes by the method and apparatus described elsewhere [1,2].

Sample Information:

1. Source not specified; best grade reagent; dried and twice distilled.
2. Obtained from the ketoesters by hydrolyzing the latter with 5% alcoholic potassium hydroxide; purified by several recrystallization from ethanol; FP = 57.8°C

Measurement Errors:

Ambient temperature: ±0.2 K.

Methodology Citations

¹ Harwood, H. J.; Ralston, A. W.; Selby, W. M.; J. Am. Chem. Soc. 63, 1916 (1941).
² Ralston, A. W.; Hoerr, C. W.; Hoffman, E. J.; J. Am. Chem. Soc. 64, 1516 (1942).