Compilation - Acetonitrile with 1-Alcohols (IUPAC SDS Volume 78)

SDS Volume (5025)

Volume 78. Acetonitrile Binary Systems, p 1063

Original Measurements

Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; Microchem. J. 9, 134-144 (1965).

Variables:

Room Temp: 296 - 347 $\pu{K}$

Prepared by:

N.V. Sazonov, V.P. Sazonov

Method/Apparatus/Procedure:

The synthetic method was used. A Reichert microscope, type RCH, equipped with a heating stage was used as described elsewhere [1]. The disappearance and reappearance of the interface between (1) and (2) could be observed without difficulty.

Source and Purity of Materials:
  1. Baker Chemical Co.; reagent No. 9011; $n_{D}^{20}$ = 1.3445, $d_{4}^{20}$ = 0.780.
  2. Some alcohols obtained from the Hormel Institute and from Lachat Chemicals; all other alcohols prepared by reduction of the corresponding methyl esters with lithium aluminum hydride; purified by gas-liquid partition chromatography.
Estimated Errors:

Ambient temperature: ±0.5 K.

References

1 Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).

Components:
  1. Acetonitrile $\ce{ C2H3N }$ [75-05-8]; NIST WebBook
  2. 1-Decanol $\ce{ C10H22O }$ [112-30-1]; NIST WebBook
    1-Undecanol $\ce{ C11H24O }$ [112-42-5]; NIST WebBook
    1-Dodecanol $\ce{ C12H26O }$ [112-53-8]; NIST WebBook
    1-Tridecanol $\ce{ C13H28O }$ [112-70-9]; NIST WebBook
    1-Tetradecanol $\ce{ C14H30O }$ [112-72-1]; NIST WebBook
    1-Pentadecanol $\ce{ C15H32O }$ [629-76-5]; NIST WebBook
    1-Hexadecanol $\ce{ C16H34O }$ [36653-82-4]; NIST WebBook
    1-Hexadecanol $\ce{ C16H34O }$ [1454-85-9]; NIST WebBook
    1-Octadecanol $\ce{ C18H38O }$ [112-92-5]; NIST WebBook
    1-Nonadecanol $\ce{ C19H40O }$ [1454-84-8]; NIST WebBook
    1-Eicosanol $\ce{ C20H42O }$ [629-96-9]; NIST WebBook
Experimental Data

Upper critical solution temperatures of the binary systems acetonitrile (1) with 1-alcohols (2)

1-Alcohols (C10-C20) $T$ (°C) $T$ ($\pu{K}$)
1-Decanol (link to XML output link to JSON output link to JSON-LD output) 23.0296.2
1-Undecanol (link to XML output link to JSON output link to JSON-LD output) 29.0302.2
1-Dodecanol (link to XML output link to JSON output link to JSON-LD output) 34.5307.7
1-Tridecanol (link to XML output link to JSON output link to JSON-LD output) 40.0313.2
1-Tetradecanol (link to XML output link to JSON output link to JSON-LD output) 44.5317.7
1-Pentadecanol (link to XML output link to JSON output link to JSON-LD output) 50.0323.2
1-Hexadecanol (link to XML output link to JSON output link to JSON-LD output) 54.5327.7
1-Hexadecanol (link to XML output link to JSON output link to JSON-LD output) 59.5332.7
1-Octadecanol (link to XML output link to JSON output link to JSON-LD output) 64.0337.2
1-Nonadecanol (link to XML output link to JSON output link to JSON-LD output) 69.0342.2
1-Eicosanol (link to XML output link to JSON output link to JSON-LD output) 74.0347.2