SDS Volume (5013)

Volume 78. Acetonitrile Binary Systems, p None

Original Measurements

Konecky, J. O.; Deal, C. H.; J. Phys. Chem. 67, 504-6 (1963).

Variables:

Room Temp: 256 - 317 $\pu{K}$

Prepared by:

N.V. Sazonov, V.P. Sazonov

Method/Apparatus/Procedure:

The synthetic (cloud point) method using sealed Pyrex tubes was employed. All values reported are an average of at least three determinations agreeing within 0.2 °C or better. No details were reported.

Source and Purity of Materials:

1. Source not specified; spectroscopic grade; not purified.
2. Prepared by the decarboxylation of perfluoro-n-octanoic acid; dried over phosphorus pentoxide and distilled on a ten plate microhelipod column at a reflux ratio of 5/1; BP = 95°C/100.1 kPa, $\rho^{25} = \pu{1718 g L-1}$.

Estimated Errors:

Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.

References

¹ Timmermans, J.; Physico-Chemical Constants of Pure Organic Compounds (Elsevier, New York, 1950).