Compilation - Nitroethane with 10-Nonadecanone (IUPAC SDS Volume 77)
SDS Volume (5005)
Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p 64
Original Measurements
Garland, F. M.; Hoerr, C. W.; Pool, W. O.; Ralston, A. W.; J. Org. Chem. 8, 344-57 (1943).
Variables:
Temperature: 293 - 327 K
Prepared by:
N.I. Lisov, N.V. Sazonov, V.P. Sazonov
Method/Apparatus/Procedure:
The synthetic method was used. The solubilities of (2) in (1) were determined in sealed tubes by the method and apparatus described in Harwood, et al. [1] and Raltston, et al. [2].
Source and Purity of Materials:
- Source not specified; best grade reagent; dried and twice distilled.
- Obtained from the ketoester by hydrolyzing the latter with 5% alcoholic potassium hydroxide; purified by several recrystallization from ethanol; f. p. = 57.8°C
References
1
Harwood, H. J.; Ralston, A. W.; Selby, W. M.; J. Am. Chem. Soc. 63, 1916 (1941).
2
Ralston, A. W.; Hoerr, C. W.; Hoffman, E. J.; J. Am. Chem. Soc. 64, 1516 (1942).
Experimental Data
Nitroethane with 10-Nonadecanone
Components:
(1) Nitroethane,
$\ce{ C2H5NO2 }$;
[79-24-3]
NIST WebBook
(2) 10-Nonadecanone,
$\ce{ C19H38O }$;
[504-57-4]
NIST WebBook
Experimental Values:
Solubility of 10-nonadecanone (2) in nitroethane (1)
| T (°C) | T (K) | MR2 (g2/100 g1) | 100w2 | x2 |
|---|---|---|---|---|
| 20.0 | 293.2 | 1.6 | 1.6 x 10-2 | 4 x 10-3 |
| 23.3 | 296.5 | - | 1.9 x 10-2 | 5 x 10-3 |
| 26.9 | 300.1 | - | 2.7 x 10-2 | 7 x 10-3 |
| 36.7 | 310.0 | - | 9.3 x 10-2 | 2.7 x 10-2 |
| 38.9 | 312.1 | - | 1.36 x 10-1 | 4.0 x 10-2 |
| 40.0 | 313.2 | 19.8 | 1.65 x 10-1 | 5.0 x 10-2 |
| 42.6 | 315.8 | - | 2.86 x 10-1 | 9.6 x 10-2 |
| 45.6 | 318.8 | - | 5.24 x 10-1 | 2.26 x 10-1 |
| 48.9 | 322.1 | - | 7.25 x 10-1 | 4.12 x 10-1 |
| 50.0 | 323.2 | 350.0 | 7.78 x 10-1 | 4.82 x 10-1 |
| 52.6 | 325.8 | - | 8.73 x 10-1 | 6.46 x 10-1 |
| 53.5 | 326.7 | - | 9.04 x 10-1 | 7.15 x 10-1 |
(*) The compilers extracted these data from the published graphs.
The solubilities of 10-nonadecanone (2) in nitroethane (1) in mass percent over the temperature range were presented in graphical form and in a table.
