SDS Volume (5005)

Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p None

Original Measurements

Garland, F. M.; Hoerr, C. W.; Pool, W. O.; Ralston, A. W.; J. Org. Chem. 8, 344-57 (1943).

Variables:

Room Temp: 293 - 327 $\pu{K}$

Prepared by:

N.I. Lisov, N.V. Sazonov, V.P. Sazonov

Method/Apparatus/Procedure:

The synthetic method was used. The solubilities of [2] in [1] were determined in sealed tubes by the method and apparatus described in Harwood, et al. [1] and Raltston, et al. [2].

Source and Purity of Materials:

1. Source not specified; best grade reagent; dried and twice distilled.
2. Obtained from the ketoester by hydrolyzing the latter with 5% alcoholic potassium hydroxide; purified by several recrystallization from ethanol; FP = 57.8°C

Estimated Errors:

Ambient temperature: ±0.2 K

References

¹ Harwood, H. J.; Ralston, A. W.; Selby, W. M.; J. Am. Chem. Soc. 63, 1916 (1941).
² Ralston, A. W.; Hoerr, C. W.; Hoffman, E. J.; J. Am. Chem. Soc. 64, 1516 (1942).