Compilation - Nitroethane with 1-Octadecanol (IUPAC SDS Volume 77)
SDS Volume (5004)
Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p None
Original Measurements
Hoerr, C. W.; Harwood, H. J.; Ralston, A. W.; J. Org. Chem. 9, 267-80 (1944).
Variables:
Room Temp: 303 - 327 $\pu{K}$
Prepared by:
N.I. Lisov, N.V. Sazonov, V.P. Sazonov
Method/Apparatus/Procedure:
The synthetic method was used. The solubility measurements were made with the equipment and in the manner described in Hoerr, et al. [1], and Ralston, et al. [2].
Source and Purity of Materials:
- Source not specified; purity not specified.
- Prepared by catalytic hydrogenation of ethyl stearate; purified by vacuum distillation; FP = 57.98°C.
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
References
1
Hoerr, C. W.; Binkerd, E. F.; Pool, W. O.; Ralston, A. W.; J. Org. Chem. 9, 68-80 (1944).
2
Ralston, A. W.; Hoerr, C. W.; Pool, W. O.; Harwood, H. J.; J. Org. Chem. 9, 102-112 (1944).
Components:
- Nitroethane, $\ce{ C2H5NO2 }$; [79-24-3] NIST WebBook
- 1-Octadecanol, $\ce{ C18H38O }$; [112-92-5] NIST WebBook
Experimental Data
The solubilities of 1-octadecanol (2) in nitroethane (1) in mass percent over the temperature range were presented in graphical form and in a table.
Solubility of 1-octadecanol (2) in nitroethane (1)
| $T$ (°C) | $T$ ($\pu{K}$) | MR2 (g2/100 g1) | 100w2 | $x_{2}$ |
|---|---|---|---|---|
| 30.0 | 303.2 | 0.1 | 1 x 10-3 | 3 x 10-4 |
| 36.1 | 309.3 | - | 0.010 | 3 x 10-3 |
| 40.0 | 313.2 | 2.7 | 0.026 | 7 x 10-3 |
| 40.7 | 313.9 | - | 0.033 | 9 x 10-3 |
| 43.9 | 317.1 | - | 0.067 | 0.020 |
| 48.5 | 321.7 | - | 0.155 | 0.048 |
| 50.0 | 323.2 | 25.4 | 0.203 | 0.066 |
| 50.9 | 324.1 | - | 0.266 | 0.091 |
| 51.5 | 324.7 | - | 0.326 | 0.118 |
| 52.2 | 325.4 | - | 0.470 | 0.198 |
| 52.5 | 325.7 | - | 0.677 | 0.368 |
| 53.8 | 327.0 | - | 0.857 | 0.625 |
(*) The compilers extracted these data from the published graphs.
