Components:
(1) Nitroethane,
C2H5NO2; [79-24-3]
NIST WebBook
(2) 1-Hexadecanol,
C16H34O; [1454-85-9]
NIST WebBook
Original Measurements
Hoerr, C. W.; Harwood, H. J.; Ralston, A. W.; J. Org. Chem. 9, 267-80 (1944).
Variables:
Ambient temperature: 293 - 319 K
Prepared by:
N.I. Lisov, N.V. Sazonov, V.P. Sazonov
Method/Apparatus/Procedure:
The synthetic method was used. The solubility measurements were made with the equipment and in the manner described in Hoerr et al.1 and Ralston et al.2
Source and Purity of Materials:
- Source not specified; purity not specified.
- Source not specified; commercial product; purified by recrystallization; f. p. = 49.62°C.
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
References
1
Hoerr, C. W.; Binkerd, E. F.; Pool, W. O.; Ralston, A. W.; J. Org. Chem. 9, 68-80 (1944).
2
Ralston, A. W.; Hoerr, C. W.; Pool, W. O.; Harwood, H. J.; J. Org. Chem. 9, 102-112 (1944).
Experimental Values:
Note: The solubilities of 1-hexadecanol (2) in nitroethane (1) in mass percent over the temperature range were presented in graphical form and in a table.Solubility of 1-hexadecanol (2) in nitroethane (1)
| T (°C) | T (K) | MR2 (g2/100 g1) | 100w2 | x2 |
|---|---|---|---|---|
| 20.0 | 293.2 | 1 x 10-1 | 1 x 10-3 | 3 x 10-4 |
| 28.8 | 302.0 | - | 1.2 x 10-2 | 4 x 10-3 |
| 30.0 | 303.2 | 1.6 | 1.4 x 10-2 | 5 x 10-3 |
| 38.4 | 311.6 | - | 9.1 x 10-2 | 3.0 x 10-2 |
| 40.0 | 313.2 | 13.4 | 1.18 x 10-1 | 4.0 x 10-2 |
| 40.5 | 313.7 | - | 1.30 x 10-1 | 4.4 x 10-2 |
| 43.5 | 316.7 | - | 2.59 x 10-1 | 9.8 x 10-2 |
| 44.3 | 317.5 | - | 3.82 x 10-1 | 1.61 x 10-1 |
| 44.8 | 318.0 | - | 6.39 x 10-1 | 3.54 x 10-1 |
| 45.0 | 318.2 | - | 7.70 x 10-1 | 5.09 x 10-1 |
| 45.7 | 318.9 | - | 8.57 x 10-1 | 6.50 x 10-1 |
(*) The compilers extracted these data from the published graphs.
