Compilation - Nitroethane with 1-Tetradecanol (IUPAC SDS Volume 77)
SDS Volume (4989)
Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p None
Original Measurements
Hoerr, C. W.; Harwood, H. J.; Ralston, A. W.; J. Org. Chem. 9, 267-80 (1944).
Variables:
Room Temp: 283 - 309 $\pu{K}$
Prepared by:
N.I. Lisov, N.V. Sazonov, V.P. Sazonov
Method/Apparatus/Procedure:
The solubility measurements were made with the equipment and in the manner described in Hoerr, et al. [1], and Ralston, et al. [2].
Source and Purity of Materials:
- Source not specified; purity not specified.
- Prepared by catalytic hydrogenation of methyl myristate; purified by vacuum distillation; FP = 38.26°C.
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
References
1
Hoerr, C. W.; Binkerd, E. F.; Pool, W. O.; Ralston, A. W.; J. Org. Chem. 9, 68-80 (1944).
2
Ralston, A. W.; Hoerr, C. W.; Pool, W. O.; Harwood, H. J.; J. Org. Chem. 9, 102-112 (1944).
Components:
- Nitroethane, $\ce{ C2H5NO2 }$; [79-24-3] NIST WebBook
- 1-Tetradecanol, $\ce{ C14H30O }$; [112-72-1] NIST WebBook
Experimental Data
The solubilities of nitroethane (1) and 1-tetradecanol (2) in mass percent including the region of immiscible solution over the temperature range were presented in graphical form and in a table.
Monotectic equilibrium occurs at 295.4 K.
Mutual solubility of nitroethane (1) and 1-tetradecanol (2)
| $T$ (°C) | $T$ ($\pu{K}$) | w1 | MR2 (g2/100 g1) | $x_{1}$ |
|---|---|---|---|---|
| 10.0 | 283.2 | - | 0.1 | - |
| 19.2 | 292.4 | - | - | - |
| 20.0 | 293.2 | - | 1.9 | - |
| 26.1 | 299.3 | - | - | - |
| 29.0 | 302.2 | - | - | - |
| 30.0 | 303.2 | - | 14.5 | - |
| 31.6 | 304.8 | - | - | - |
| 32.6 | 305.8 | 20.3 | - | 0.421 |
| 32.7 | 305.9 | - | - | - |
| 33.3 | 306.5 | 30.7 | - | 0.558 |
| 33.7 | 307.0 | - | - | - |
| 33.7 | 307.0 | 12.3 | - | 0.286 |
| 34.6 | 307.8 | 41.6 | - | 0.670 |
| 34.9 | 308.1 | - | - | - |
| 35.7 | 308.9 | 5.2 | - | 0.135 |
(*) The compilers extracted these data from the published graphs.
(a) Solid-liquid equilibrium
(b) Liquid-liquid equilibrium.
