SDS Volume (4986)
Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p None
Original Measurements
Hoerr, C. W.; Ralston, A. W.; J. Org. Chem. 9, 329-37 (1944).
Variables:
Room Temp: 273 - 323 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The synthetic method, as described in Hoerr, et al. [1], was used. No details were reported.
Source and Purity of Materials:
- Source not specified; purity not specified; dried and twice distilled.
- Source not specified; purified according to Pool and Ralston [2], FP = 54.15°C.
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
References
1
Hoerr, C. W.; Binkerd, E. F.; Pool, W. O.; Ralston, A. W.; J. Org. Chem. 9, 68-80 (1944).
2
Pool, W. O.; Ralston, A. W.; Ind. Eng. Chem. 34, 1104 (1942).
Components:
- Nitroethane, $\ce{ C2H5NO2 }$; [79-24-3] NIST WebBook
- Tetradecanoic acid, $\ce{ C14H28O2 }$; [544-63-8] NIST WebBook
Experimental Data
Solubility of tetradecanoic acid (2) in nitroethane (1)
| $T$ (°C) | $T$ ($\pu{K}$) | MR2 (g2/100 g1) | 100w2 | $x_{2}$ |
|---|---|---|---|---|
| 0.0 | 273.2 | 0.3 | 3 x 10-3 | 1 x 10-3 |
| 10.0 | 283.2 | 0.5 | 5 x 10-3 | 2 x 10-3 |
| 20.0 | 293.2 | 1.2 | 0.012 | 3 x 10-3 |
| 30.0 | 303.2 | 3.3 | 0.032 | 0.011 |
| 40.0 | 313.2 | 10.7 | 0.097 | 0.034 |
| 50.0 | 323.2 | 1.18 x 103 | 0.922 | 0.795 |
