SDS Volume
Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p None
Source Publication
Hoerr, C. W.; Ralston, A. W.; J. Org. Chem. 9, 329-37 (1944).
Conditions:
Room Temp: 273 - 313 $\pu{K}$
Compilers:
Methodology:
The synthetic method, as described in Hoerr, et al. [1], was used. No details were reported.
Sample Information:
- Source not specified; purified according to Hoerr et al. [1]. (dried and twice distilled).
- Source not specified; purified according to Pool and Ralston [2], FP = 43.92°C.
Measurement Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Methodology Citations
1
Hoerr, C. W.; Binkerd, E. F.; Pool, W. O.; Ralston, A. W.; J. Org. Chem. 9, 68-80 (1944).
2
Pool, W. O.; Ralston, A. W.; Ind. Eng. Chem. 34, 1104 (1942).
System Components:
- Nitroethane, $\ce{ C2H5NO2 }$; [79-24-3] NIST WebBook
- Dodecanoic acid, $\ce{ C12H24O2 }$; [143-07-7] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | MR2 (g2/100 g1) | 100w2 | $x_{2}$ |
|---|---|---|---|---|
| 0.0 | 273.2 | 1.9 | 0.018 | 7 x 10-3 |
| 10.0 | 283.2 | 2.8 | 0.027 | 0.010 |
| 20.0 | 293.2 | 5.4 | 0.051 | 0.020 |
| 30.0 | 303.2 | 16.3 | 0.140 | 0.058 |
| 40.0 | 313.2 | 1.46 x 103 | 0.936 | 0.846 |
