SDS Volume (4967)

Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p None

Original Measurements

Hwa, S. C. P.; Techo, R.; Ziegler, W. T.; J. Chem. Eng. Data 8, 409-11 (1963).

Variables:

Room Temp: 275 - 326 $\pu{K}$

Prepared by:

N.I. Lisov, V.P. Sazonov

Method/Apparatus/Procedure:

The synthetic and analytical methods were used as described in Vold and Vold [1]. The analytical method consisted of withdrawing a sample from each of the coexisting phases from an equilibrium cell in a constant temperature bath, and analyzing the samples by gas chromatographic techniques. The temperature of the bath was controlled to $\pu{\pm 0.05 K}$.

Source and Purity of Materials:

1. Commercial Solvents Corp.; purity 96 mole% with 3.9 mole% of 2-nitropropane; not purified.
2. Phillips Petroleum Co.; purity > 99mole%; not purified.

Estimated Errors:

Ambient temperature: to ±0.1 K (synthetic method).
Mass concentration (m/v) (1): Composition: ±0.5 mass% (analytical method).

References

¹ Vold, R. D.; Vold, M. J.; Physical Methods of Organic Chemistry, Vol. 1 (Interscience, New York, 1945).