SDS Volume (492)

Volume 37. Hydrocarbons in Water and Seawater, Part I, p 429

Original Measurements

Sutton, C.; Calder, J. A.; J. Chem. Eng. Data 1975, 20, 320-2.

Variables:

Temperature: 25 °C
Salinity: 34.5 g salts/kg sln

Prepared by:

M. Kleinschmidt

Method/Apparatus/Procedure:

A test tube containing (1) was placed in a flask containing (2) thus allowing for equilibration through the vapor phase. The saturated solution wa extracted with hexane and analyzed by gas chromatography.

Source and Purity of Materials:
  1. From either Aldrich Chemical Co. or Matheson Coleman and Bell, 99+% pure.
  2. made from doubly distilled water and salts 99+% pure.
References

1 Lyman, J.; Fleming, R. H.; J. Mar. Res. 1940, 3, 135.

Toluene with Artificial seawater

Components:

(1) Toluene, $\ce{ C7H8 }$; [108-88-3] NIST WebBook
(2) Seawater, $\ce{ H2O }$; [7732-18-5(C)] NIST WebBook

Experimental Values:

The solubility of toluene in artificial seawater is reported to be 379.3 mg(1)/kg sln. The corresponding mass percent and mole fraction, x1 calculated by the compiler are 0.3793 g(1)/100 g sln and 7.61 × 10-5 assuming the artificial seawater composition of ref 1.

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