SDS Volume
Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p None
Source Publication
Rakhmanova, V. A.; Kozlov, L. M.; Chem. Technol. Fuels Oils 6(8), 572-576 (1968).
Conditions:
Room Temp: 298 - 319 $\pu{K}$
Compilers:
Methodology:
The synthetic method was used. No details were reported.
Sample Information:
- Source not specified; purity not specified; purified.
- Source not specified; purity not specified; BP = 383.8°C, MP = 47.7°C.
Measurement Errors:
Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
System Components:
- 2-Nitrobutane, $\ce{ C4H9NO2 }$; [600-24-8] NIST WebBook
- Tricosane, $\ce{ C23H48 }$; [638-67-5] NIST WebBook
Experimental Data
No region of liquid-liquid immiscibility was observed. The solubility of 2-nitrobutane (1) and tricosane (2) in mass percent over the specified temperature range were presented in a graphical form in the original publication. The authors at the request of the compilers provided the numerical data in the table below.
| $T$ (°C) | $T$ ($\pu{K}$) | 100w1 | $x_{1}$ |
|---|---|---|---|
| 25.0 | 298.2 | 98.3 | 0.995 |
| 30.0 | 303.2 | 96.5 | 0.989 |
| 35.0 | 308.2 | 92.5 | 0.975 |
| 38.7 | 311.9 | 85.0 | 0.947 |
| 40.5 | 313.7 | 73.7 | 0.898 |
| 40.8 | 314.0 | 64.5 | 0.851 |
| 41.1 | 314.3 | 53.3 | 0.782 |
| 41.3 | 314.5 | 41.7 | 0.693 |
| 41.7 | 314.9 | 31.7 | 0.594 |
| 42.5 | 315.7 | 23.0 | 0.485 |
| 44.0 | 317.2 | 13.7 | 0.333 |
| 46.0 | 319.2 | 5.8 | 0.162 |
