Compilation - 2-Nitropropane with Nonane (IUPAC SDS Volume 77)
SDS Volume (4909)
Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p 111
Original Measurements
Variables:
Temperature: 254 - 269 K
Prepared by:
Method/Apparatus/Procedure:
The synthetic method was used. The solutions of (1) and (2) were sealed in 5-mL glass vials. The cloud points were observed visually in an acetone bath slowly cooled by the addition of portions of dry ice. Temperatures were observed on an alcohol thermometer.
Source and Purity of Materials:
- Eastman; practical grade; distilled at 60°C/13.3 kPa.
- Phillips; purity 99 mol%.
Experimental Data
2-Nitropropane with Nonane
Components:
(1) 2-Nitropropane,
$\ce{ C3H7NO2 }$;
[79-46-9]
NIST WebBook
(2) Nonane,
$\ce{ C9H20 }$;
[111-84-2]
NIST WebBook
Experimental Values:
Mutual solubility of 2-nitropropane (1) and nonane (2)
| T (°C) | T (K) | w1 | x1 |
|---|---|---|---|
| -19.1 | 254.1 | - | - |
| -7.8 | 265.4 | - | - |
| -5.3 | 267.9 | - | - |
| -4.8 | 268.4 | 33.9 | 4.25 x 10-1 |
| -4.6 | 268.6 | - | - |
| -4.5 | 268.7 | - | - |
Mutual solubility of 2-nitropropane (1) and nonane (2)
| T (°C) | T (K) | 100w1 | x1 |
|---|---|---|---|
| -19.1 | 254.1 | 81.7 | 8.65 x 10-1 |
| -7.8 | 265.4 | 70.5 | 7.75 x 10-1 |
| -5.3 | 267.9 | 59.6 | 6.80 x 10-1 |
| -4.8 | 268.4 | - | - |
| -4.6 | 268.6 | 45.9 | 5.50 x 10-1 |
| -4.5 | 268.7 | - | - |
