Components:

(1) 2-Nitropropane, C3H7NO2; [79-46-9] NIST WebBook
(2) Water, H2O; [7732-18-5] NIST WebBook

Original Measurements

Stephenson, R. M.; J. Chem. Eng. Data 37, 80-95 (1992).

Variables:

Ambient temperature: 273 - 363 K

Prepared by:

V.P. Sazonov

Method/Apparatus/Procedure:

No details were reported.

Source and Purity of Materials:
  1. Aldrich Chemical; not purified; purity 96 mass%.
  2. Not specified.
Estimated Errors:

Ambient temperature: to ±0.1 K
Mass concentration (m/v) (1): 0.03 mass%.

Experimental Values:
Note: Below 10°C, organic-rich phase on bottom; above 10°C, organic-rich phase top.
Mutual solubility of 2-nitropropane (1) and water (2)
T (°C) T (K) 100w1 x1
0.0 273.2 3.07 6.4 x 10-3
19.7 282.9 1.8 3.7 x 10-3
30.9 304.1 1.7 3.5 x 10-3
40.0 313.2 1.78 3.7 x 10-3
50.5 323.7 1.79 3.7 x 10-3
61.1 334.3 2.07 4.3 x 10-3
70.6 343.8 2.09 4.3 x 10-3
81.0 354.2 2.26 4.7 x 10-3
90.2 363.4 2.36 4.9 x 10-3

Mutual solubility of 2-nitropropane (1) and water (2)
T (°C) T (K) 100w1 x1
0.0 273.2 99.66 9.834 x 10-1
19.7 282.9 99.51 9.762 x 10-1
30.9 304.1 99.35 9.687 x 10-1
40.0 313.2 99.3 9.663 x 10-1
50.5 323.7 99.07 9.556 x 10-1
61.1 334.3 98.73 9.402 x 10-1
70.6 343.8 98.55 9.322 x 10-1
81.0 354.2 98.09 9.122 x 10-1
90.2 363.4 97.77 8.987 x 10-1

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