Compilation - 1-Nitropropane with Paraffins (IUPAC SDS Volume 77)
SDS Volume (4900)
Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p 106
Original Measurements
Kozlov, L. M.; Volpert, V. I.; Chem. Technol. Fuels Oils (4), 264 (1968).
Variables:
Temperature: 255 - 313 K
Prepared by:
Method/Apparatus/Procedure:
The method, described in Poole [1] was used. No experimental details given.
Source and Purity of Materials:
- Not specified.
- Obtained by separation of narrow fraction with b. p.* = (196 to 270)°C, b. p.** = (300 to 365)°C from a wide fraction of diesel fuel; m. p.* = 13.2°C and m. p.** = 28.0°C; *** and **** obtained by separation of the third oil fraction of Tuimazin crude
References
Experimental Data
1-Nitropropane with Paraffins
Components:
(1) 1-Nitropropane,
$\ce{ C3H7NO2 }$;
[108-03-2]
NIST WebBook
(2) Paraffins,
[8002-74-2]
NIST WebBook
Experimental Values:
Solubility of paraffins (2) in 1-nitropropane (1)
| T (°C) | T (K) | MR2 (g2/100 g1) | 100w2 | x2 |
|---|---|---|---|---|
| -18.1 | 255.1 | 1 x 10-1 | 1 x 10-1 | 4 x 10-4 |
| -13.6 | 259.6 | 3 x 10-1 | 3 x 10-1 | 1.2 x 10-3 |
| -10.0 | 263.2 | 5 x 10-1 | 5 x 10-1 | 2.0 x 10-3 |
| -8.3 | 264.9 | 7 x 10-1 | 7 x 10-1 | 2.9 x 10-3 |
| -3.6 | 269.6 | 1.0 | 1.0 | 4.1 x 10-3 |
| 6.1 | 279.3 | 3.0 | 2.9 | 1.21 x 10-2 |
| 10.0 | 283.2 | 5.0 | 4.8 | 2.02 x 10-2 |
| 12.6 | 285.8 | 7.0 | 6.5 | 2.76 x 10-2 |
| -1.6 | 271.6 | 1 x 10-1 | 1 x 10-1 | 4 x 10-4 |
| 5.2 | 278.4 | 3 x 10-1 | 3 x 10-1 | 1.1 x 10-3 |
| 8.9 | 282.1 | 5 x 10-1 | 5 x 10-1 | 1.8 x 10-3 |
| 13.1 | 286.3 | 7 x 10-1 | 7 x 10-1 | 2.5 x 10-3 |
| 15.8 | 289.0 | 1.0 | 1.0 | 3.5 x 10-3 |
| 25.6 | 298.8 | 3.9 | 3.8 | 1.36 x 10-2 |
| 27.1 | 300.3 | 5.0 | 4.8 | 1.73 x 10-2 |
| 4.8 | 278.0 | 5.5 x 10-2 | 5.5 x 10-2 | 2 x 10-4 |
| 7.8 | 281.0 | 7 x 10-2 | 7 x 10-2 | 2 x 10-4 |
| 11.6 | 284.8 | 1.1 x 10-1 | 1.1 x 10-1 | 3 x 10-4 |
| 20.0 | 293.2 | 3 x 10-1 | 3 x 10-1 | 9 x 10-4 |
| 26.3 | 299.5 | 7 x 10-1 | 7 x 10-1 | 2.1 x 10-3 |
| 28.8 | 302.0 | 1.3 | 1.3 | 3.9 x 10-3 |
| 2.3 | 275.5 | 1 x 10-2 | 1 x 10-2 | 3 x 10-5 |
| 15.3 | 288.5 | 5 x 10-2 | 5 x 10-2 | 1 x 10-4 |
| 20.0 | 293.2 | 8 x 10-2 | 8 x 10-2 | 2 x 10-4 |
| 23.8 | 297.0 | 1 x 10-1 | 1 x 10-1 | 3 x 10-4 |
| 32.0 | 305.2 | 3 x 10-1 | 3 x 10-1 | 8 x 10-4 |
| 34.3 | 307.5 | 5 x 10-1 | 5 x 10-1 | 1.3 x 10-3 |
| 38.0 | 311.2 | 7 x 10-1 | 7 x 10-1 | 1.9 x 10-3 |
| 40.0 | 313.2 | 1.0 | 1.0 | 2.7 x 10-3 |
The solubilities of paraffins in 1-nitropropane over the indicated temperature range were presented in graphically as a plot of temperature against log solubility. The data in the table below were extracted compilers from the reported graphs.
NOTE: Footnotes explained in Source and Purity of Materials section, below.
