NIST-IUPAC Solubility Data Series

Nitroethane with Nitromethane, 1,2-Ethanediol, 1-Dodecanol and Water (IUPAC SDS Volume 77)

SDS Volume

Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p None

Source Publication

Das, B. K.; Griffiths, R. B.; J. Chem. Phys. 70, 5555-66 (1979).

Conditions:

Room Temp: 311 - 315 $\pu{K}$

Compilers:

N.I. Lisov, V.P. Sazonov

Methodology:

The analytical method was used. The liquid mixture was placed in a glass tube 12.5 cm long with an inside diameter of 1.4 cm. The total mass of the sample was 8 to 10 g. The tube was closed with a Bakelite screw cap. The entire tube was mounted vertically and submerged in a water bath. After every change in temperature the sample was vigorously stirred several times using a Teflon-coated magnetic stirrer inside the tube. It was then necessary to wait from a few hours to a day for the different liquid phases to segregate into layers. Samples, typically 0.1 mL, of the different phases were removed using a syringe with a stainless steel needle. The syringe was first, if necessary, heated uniformly to a temperature (typically 50 °C) above that of the bath to prevent phase separation in the liquid. Analyses of the compositions of four coexisting phases were determined using gas chromatography.

Sample Information:

Fisher Chemicals; reagent grade.
Aldrich Chemicals; reagent grade.
Bauer Chemicals; reagent grade; contained some water. (4) Eastman Chemicals; reagent grade. (5) Distilled; impurity less than 0.4 mass%.

Measurement Errors:

Ambient temperature: ±0.01 K.
Mass concentration (m/v) (1): Composition: relative error less than 5%.

System Components:

Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
Nitroethane, $\ce{ C2H5NO2 }$; [79-24-3] NIST WebBook
1,2-Ethanediol, $\ce{ C2H6O2 }$; [107-21-1] NIST WebBook
1-Dodecanol, $\ce{ C12H26O }$; [112-53-8] NIST WebBook
Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook

Experimental Data

The usual order of the four phases in the sample tube. L₁ - upper liquid phase, L₂ - second from the top liquid phase, L₃ - second from the bottom liquid phase, L₄ - lower liquid phase.

$T$ (°C)	$T$ ($\pu{K}$)	100w₁	100w₂	100w₃	100w₄	$x_{1}$	$x_{2}$	$x_{3}$	$x_{4}$
37.58	310.73	31.4	4.3	32.0	29.4	0.362	0.040	0.363	0.110
37.58	310.73	31.5	3.9	41.6	18.5	0.326	0.033	0.424	0.063
37.58	310.73	56.9	7.4	21.1	12.6	0.602	0.064	0.219	0.044
37.58	310.73	30.3	3.8	48.1	12.7	0.297	0.030	0.463	0.041
37.92	311.07	30.5	4.4	30.6	31.8	0.364	0.043	0.359	0.124
37.92	311.07	45.9	6.4	30.0	15.0	0.487	0.055	0.313	0.052
37.92	311.07	55.4	7.2	22.5	12.7	0.585	0.062	0.233	0.044
37.92	311.07	29.5	3.6	50.0	11.3	0.284	0.028	0.473	0.036
38.55	311.70	33.7	3.9	26.8	32.4	0.398	0.037	0.311	0.125
38.55	311.70	34.9	3.7	34.9	22.0	0.369	0.032	0.362	0.076
38.55	311.70	63.3	6.9	18.8	8.4	0.640	0.057	0.187	0.028
38.55	311.70	33.2	3.4	48.6	8.3	0.306	0.025	0.441	0.025
38.84	311.99	28.0	3.9	27.4	37.7	0.346	0.039	0.333	0.153
38.84	311.99	35.9	4.6	33.2	22.7	0.391	0.041	0.355	0.081
38.84	311.99	54.7	6.6	22.8	13.3	0.572	0.056	0.234	0.046
38.84	311.99	27.5	2.8	54.4	8.6	0.253	0.021	0.492	0.026
39.01	312.16	33.8	2.9	30.2	29.2	0.383	0.027	0.336	0.108
39.01	312.16	37.0	2.8	39.3	15.5	0.367	0.023	0.383	0.050
39.01	312.16	61.1	5.1	20.2	11.0	0.627	0.043	0.204	0.037
39.01	312.16	34.6	2.5	46.9	9.3	0.320	0.019	0.426	0.028
39.26	312.41	32.2	2.7	31.5	29.5	0.362	0.025	0.348	0.109
39.26	312.41	33.9	2.6	36.5	22.4	0.359	0.022	0.380	0.078
39.26	312.41	58.4	4.6	21.1	13.1	0.604	0.039	0.215	0.044
39.26	312.41	32.0	2.5	49.0	10.2	0.299	0.019	0.451	0.031
39.39	312.54	32.4	4.1	27.9	33.1	0.391	0.040	0.331	0.131
39.39	312.54	40.9	4.8	29.2	22.2	0.451	0.043	0.317	0.080
39.39	312.54	53.7	6.0	23.4	14.5	0.570	0.052	0.244	0.050
39.39	312.54	28.9	2.7	54.5	6.9	0.260	0.020	0.483	0.020
39.40	312.55	37.2	3.7	31.8	23.4	0.404	0.033	0.340	0.083
39.40	312.55	37.0	3.6	35.6	19.4	0.383	0.030	0.363	0.066
39.40	312.55	55.8	5.5	22.1	13.9	0.583	0.047	0.227	0.048
39.40	312.55	29.4	2.5	53.9	7.0	0.265	0.018	0.477	0.021
39.50	312.65	36.3	3.6	26.7	30.0	0.420	0.033	0.304	0.114
39.50	312.65	38.2	3.6	33.3	20.6	0.401	0.031	0.344	0.071
39.50	312.65	58.0	5.6	21.1	12.6	0.603	0.047	0.216	0.043
39.50	312.65	30.2	2.3	53.8	6.2	0.269	0.017	0.471	0.018
39.76	312.91	26.7	2.5	25.0	42.4	0.339	0.026	0.312	0.176
39.76	312.91	35.5	3.0	37.0	19.6	0.365	0.025	0.374	0.066
39.76	312.91	55.2	4.5	22.5	14.7	0.575	0.038	0.231	0.050
39.76	312.91	29.7	2.5	45.7	15.6	0.285	0.020	0.432	0.049
39.97	313.12	30.8	2.3	25.3	38.3	0.377	0.023	0.305	0.154
39.97	313.12	38.4	2.5	38.8	14.7	0.374	0.020	0.371	0.047
39.97	313.12	60.4	3.9	21.2	11.5	0.614	0.032	0.212	0.038
39.97	313.12	36.4	2.3	44.2	9.9	0.333	0.017	0.397	0.030
40.02	313.17	31.2	2.6	46.4	25.8	0.342	0.023	0.393	0.093
40.02	313.17	35.9	2.8	36.0	19.8	0.364	0.023	0.359	0.066
40.02	313.17	54.2	4.2	25.6	13.0	0.556	0.035	0.258	0.044
40.02	313.17	29.7	2.0	53.1	6.9	0.261	0.014	0.460	0.020
40.08	313.23	20.2	1.5	27.2	45.0	0.269	0.016	0.402	0.196
40.08	313.23	44.6	2.1	37.3	17.4	0.452	0.017	0.311	0.058
40.08	313.23	52.3	2.5	22.4	13.9	0.528	0.021	0.272	0.046
40.08	313.23	31.7	1.5	50.0	5.1	0.274	0.011	0.452	0.014
40.15	313.30	32.1	2.2	24.3	35.2	0.384	0.021	0.320	0.138
40.15	313.30	40.7	2.3	36.0	14.5	0.399	0.018	0.360	0.047
40.15	313.30	59.2	3.6	22.1	11.6	0.601	0.030	0.224	0.039
40.15	313.30	32.8	1.6	40.0	8.2	0.295	0.012	0.443	0.024
40.28	313.43	31.5	2.2	30.7	38.4	0.384	0.022	0.292	0.153
40.28	313.43	41.1	2.5	31.2	15.3	0.408	0.020	0.351	0.050
40.28	313.43	59.2	4.0	27.4	11.5	0.601	0.033	0.221	0.038
40.28	313.43	42.3	2.7	53.1	9.1	0.396	0.021	0.368	0.028
40.54	313.69	31.4	3.0	29.3	32.0	0.358	0.028	0.329	0.120
40.54	313.69	39.7	3.5	31.3	20.5	0.411	0.029	0.319	0.069
40.54	313.69	50.7	4.4	26.7	14.5	0.520	0.037	0.269	0.049
40.54	313.69	26.8	2.0	57.0	4.5	0.226	0.014	0.472	0.012
40.78	313.93	33.3	2.5	30.6	30.3	0.385	0.023	0.348	0.115
40.78	313.93	42.0	2.7	31.2	19.7	0.435	0.023	0.318	0.067
40.78	313.93	51.5	3.4	28.3	13.5	0.525	0.028	0.284	0.045
40.78	313.93	26.7	1.4	58.0	5.4	0.231	0.010	0.494	0.015
40.85	314.00	33.5	2.2	27.4	33.2	0.391	0.021	0.315	0.127
40.85	314.00	43.2	2.5	31.6	18.0	0.440	0.021	0.317	0.060
40.85	314.00	53.6	3.0	25.4	14.4	0.545	0.025	0.254	0.048
40.85	314.00	34.3	1.7	49.9	6.4	0.304	0.012	0.435	0.019
41.00	314.15	29.7	0.2	24.5	41.5	0.365	2 x 10^-3	0.296	0.167
41.00	314.15	46.0	0.5	34.6	12.7	0.436	4 x 10^-3	0.322	0.039
41.00	314.15	56.2	0.7	25.8	12.8	0.553	6 x 10^-3	0.250	0.041
41.00	314.15	39.2	0.3	43.4	8.8	0.348	2 x 10^-3	0.378	0.026
41.13	314.28	31.5	2.3	24.2	37.8	0.376	0.022	0.284	0.148
41.13	314.28	37.2	2.5	30.9	24.3	0.392	0.021	0.320	0.084
41.13	314.28	46.1	3.2	26.0	20.4	0.483	0.027	0.268	0.070
41.13	314.28	27.5	1.7	56.8	4.6	0.233	0.012	0.473	0.013
41.17	314.32	29.7	0.2	24.1	41.7	0.363	2 x 10^-3	0.290	0.167
41.17	314.32	47.4	0.6	28.8	17.9	0.474	5 x 10^-3	0.283	0.059
41.17	314.32	51.8	0.6	28.1	14.4	0.510	5 x 10^-3	0.272	0.046
41.17	314.32	37.3	0.1	45.4	8.8	0.330	1 x 10^-3	0.395	0.026
41.29	314.44	31.7	0.5	25.1	39.3	0.390	5 x 10^-3	0.304	0.159
41.29	314.44	47.0	0.7	32.3	15.3	0.467	6 x 10^-3	0.316	0.050
41.29	314.44	53.3	0.8	27.7	13.8	0.532	6 x 10^-3	0.272	0.045
41.29	314.44	40.1	0.4	44.2	8.2	0.361	3 x 10^-3	0.392	0.024
41.68	314.83	36.9	2.7	25.3	30.6	0.415	0.025	0.280	0.113
41.68	314.83	39.3	3.0	26.1	27.1	0.429	0.027	0.280	0.097
41.68	314.83	43.8	3.2	27.7	20.4	0.452	0.027	0.281	0.069
41.68	314.83	26.2	1.5	57.8	4.2	0.217	0.010	0.472	0.011

IUPAC-NIST Solubility Data Series, SRD 106