Nitroethane with 1,2-Ethanediol and 1-Decanol (IUPAC SDS Volume 77)

SDS Volume

Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p None

Source Publication

Francis, A. W.; J. Phys. Chem. 60, 20-7 (1956).

Conditions:

Room Temp: 273 - 283 $\pu{K}$

Compilers:

N.I. Lisov, V.P. Sazonov

Methodology:

The synthetic method was used. Observations were made after vigorous shaking in glass-stoppered tubes (15 mL capacity) immersed in water baths in large Dewar flasks. Temperature was adjusted by adding small amounts of cooler or warmer water. Filling started with 5 mL of one reagent followed by small additions of the other two, usually alternately, to maintain a trace of lower or upper layer, until the composition of a plait point was reached or the tube was full (see Tables 1 and 2).

Sample Information:
  1. Eastman Kodak Co., distilled with 30 cm column with reflux; BP = 114-115°C; MP = -78°C; $n_{D}^{20}$ = 1.3920, $\rho^{20} = \pu{1046.9 g L-1}$.
  2. Purified by crystallization; MP = -13.3°C; $n_{D}^{20}$ = 1.4315, $\rho^{25} = \pu{1110.1 g L-1}$.
  3. Purified by crystallization; MP = 6.8°C; $n_{D}^{20}$ = 1.4372, $\rho^{20} = \pu{831.8 g L-1}$.
Measurement Errors:

Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.

System Components:
  1. Nitroethane, $\ce{ C2H5NO2 }$; [79-24-3] NIST WebBook
  2. 1,2-Ethanediol, $\ce{ C2H6O2 }$; [107-21-1] NIST WebBook
  3. 1-Decanol, $\ce{ C10H22O }$; [112-30-1] NIST WebBook
Experimental Data
$T$ (°C) $T$ ($\pu{K}$) 100w1 100w2 $x_{1}$ $x_{2}$
10.0283.2 9a62 0.090.77
10.0283.2 88E+1 0.070.88
10.0283.2 7.547.5 0.0870.666
10.0283.2 358 0.490.14
10.0283.2 256E+1 0.240.69
10.0283.2 53a8 0.650.12
10.0283.2 54a26 0.570.33
0.0273.2 1E+113 0.160.25
0.0273.2 98E+1 0.080.87
10.0283.2 828 0.850.10
0.0273.2 8.546.5 0.100.653
6.0279.2 54b24 0.580.31
6.0279.2 5E+124 0.550.32
0.0273.2 28.534.5 0.3250.475
0.0273.2 11a6E+1 0.110.75
6.0279.2 7.547.5 0.0870.666
6.0279.2 4532.5 0.470.414
6.0279.2 3416 0.440.25
6.0279.2 1971 0.170.78
6.0279.2 1E+1a61 0.100.76
6.0279.2 88E+1 0.070.88
0.0273.2 844 0.890.05

(a) Plait point of binodal curve.

(b) Col. A col is a point in a ternary system where two separate binodal curves meet at their respective plait points.

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