SDS Volume
Volume 77. Nitroalkanes with Water or Organic Solvents: Binary and Multicomponent Systems, p None
Source Publication
Pol'shinskii, V. V.; Kozlov, L. M.; Chem. Technol. Fuels Oils 1970, 6(10), 730-734.
Conditions:
Room Temp: 279 - 377 $\pu{K}$
Compilers:
Methodology:
The method, described in Bondarev and Kozlov [1] was used. No experimental details given.
Sample Information:
- Source not specified; purity not specified; purified; $n_{D}^{20}$ = 1.3919; $d_{4}^{20}$ = 1.0596.
- Obtained by distillation of Tuimazin crude between 440 and 520°C; stocks obtained by division of oil fraction on silica gel by liquid chromatography.
Measurement Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Methodology Citation
1 Bondarev, S. V.; Kozlov, L. M.; Chem. Technol. Fuels Oils 4(10), 720-724 (1968)
System Components:
- Nitroethane, $\ce{ C2H5NO2 }$; [79-24-3] NIST WebBook
- Oil fraction of Tuimazin crude, [mix-06] NIST WebBook
Experimental Data
Values of critical solution temperatures of nitroethane (1) and stocks of fractions of Tuimazin crude (2) are presented over the temperature range in graphical form.
| $T$ (°C) | $T$ ($\pu{K}$) | $\rho, (20^{\circ}C)$ (g/cm3) | $n (\pu{20 ^{\circ}C},\rm{D})$ |
|---|---|---|---|
| 6 | 279 | 1.0232-1.0479 | 1.5787-1.5979 |
| 30 | 303 | 0.9706-0.9921 | 1.5430-1.5623 |
| 64 | 337 | 0.9176 | 1.5090 |
| 104 | 377 | 0.8195-0.8667 | 1.420-1.4756 |
(*) n(70°C,D)
