SDS Volume

Volume 73. Metal and Ammonium Formate Systems, p None

Source Publication

Nadzharyan, K. A.; Itkina, L. S.; Lepeshkov, I. N.; Zh. Neorg. Khim. 26, 519 (1981).

Conditions:

Room Temp: Composition at 25 °C

Compilers:

St. Trendafilova, Chr. Balarew

Methodology:

The isothermal method was used. The mixtures were placed in glass vessels in a thermostat and stirred mechanically. Equilibrium was reached in three weeks. The potassium content of both phases was determined by the tetraphenylborate method. The cadmium content was determined complexometrically. The composition of the solid phases was determined by Schreinemakers' method.

Sample Information:
  1. $\ce{KCHO2}$ was prepared by neutralizing 85% formic acid with p.a. grade$\ce{KOH}$. Cadmium formate was obtained from p.a. grade cadmium carbonate.
Measurement Errors:

Ambient temperature: The temperature was kept constant to within ±0.1°C.

System Components:
  1. Potassium formate, $\ce{ KCHO2 }$; [590-29-4] NIST WebBook
  2. Cadmium formate, $\ce{ Cd(CHO2)2 }$; [4464-23-7] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
100w1 100w2 m1 (mol/kg) b m2 (mol/kg) b Phase (s) () a
81.82- 53.51-A
79.160.99 47.420.246A + B
76.091.08 39.630.234B
70.061.35 29.140.233B
62.192.71 21.070.381B
60.553.28 19.910.448B
58.674.50 18.940.604B
57.385.57 18.420.743B
56.156.09 17.680.797B
51.4910.53 16.131.373B + C
49.5910.07 14.621.233C
41.8610.14 10.371.043C
35.5411.99 8.0541.129C
29.8814.79 6.5401.136C
25.2420.22 5.5031.831C
22.1424.39 4.9232.253C + D
20.7721.00 4.2411.781D
18.4119.40 3.5201.541D
12.7316.09 2.1271.117D
-14.10 -0.811D

(a) The solid phases are: A = KCHO2; B = K3Cd(CHO2)5; C = KCd(CHO2)3; D = Cd(CHO2)2·2H2O.

(b) The molality values were calculated by the compilers.

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