Compilation - Chlorobenzene with Water (IUPAC SDS Volume 20)
SDS Volume (48)
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 165
Original Measurements
Andrews, L. J.; Keefer, R. M.; J. Am. Chem. Soc. 1950, 72(7), 3113-6.
Variables:
Room Temp: 25.0 °C
Prepared by:
Method/Apparatus/Procedure:
Water was saturated with chlorobenzene in a glass stoppered Erlenmeyer flask by rotating the flask in a constant temperature bath for 20 hours. The saturated solution was extracted with n-hexane for analysis. The optical density of the extract was measured against a n-hexane standard using a Beckman spectrophotometer [1].
Source and Purity of Materials:
- Eastman Kodak Co., commercial reagent, BP = 131.9-132°C, fractionated before use.
- Not specified.
Estimated Errors:
Ambient temperature: ±0.1 K (compiler).
Mass concentration (m/v) (1): ±10% (compiler).
References
1 Andrews, L. J.; Keefer, R. M.; J. Am. Chem. Soc. 1949, 71, 3644-77.
Components:
- Chlorobenzene, $\ce{ C6H5C1 }$; [108-90-7] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | Cm1 (g(1)/dm3) | $C_{1}$ (mol/dm3) | $x_{1}$ |
|---|---|---|---|
| 25 | 0.50 | 4.44 x 10-3 | 8.03 x 10-5 |
(a) Reported.
(b) Calculated by F. W. Getzen.
(c) Calculated by the compiler.
