SDS Volume

Volume 73. Metal and Ammonium Formate Systems, p None

Source Publication

Chaplygina, N. M.; Portnova, S. M.; Zh. Neorg. Khim. 30, 225-228 (1985).

Conditions:

Room Temp: Composition at 50 °C

Compiler:

Chr. Balarew

Methodology:

The isothermal method was used. Equilibrium was attained in two weeks. The yttrium content was determined by titration with Complexone III. The composition of the solid phases was determined by X-ray diffraction, by thermogravimetry and by IR spectroscopy [1].

Sample Information:
  1. The yttrium formate dihydrate was prepared by the reaction of $\ce{Y2O3}$ with dilute A.R. grade formic acid [1].
Measurement Errors:

Ambient temperature: The temperature was controlled to within ±0.1°C.2

Methodology Citations

1 Itkina, L. S.; Petrova, E. V.; Antsyshkina, A. S.; Zh. Neorg. Khim. 26, 3112-7 (1981).
2 Itkina, L. S.; Nadzharyan, K. A.; Zh. Neorg. Khim. 26, 515 (1981).

System Components:
  1. Yttrium(III) formate, $\ce{ Y(CHO2)3 }$; [15331-71-2] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) 100w1 m1 (mol/kg) a Phase (s) ()
50 26.37 1.599Y(CHO2)3·2H2O

(a) This value was calculated by the compiler.

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