SDS Volume
Volume 73. Metal and Ammonium Formate Systems, p None
Source Publication
Groschuff, E.; Ber. Dtsch. Chem. Ges. 36, 1783-95 (1903).
Conditions:
Composition and temperature
Compiler:
Methodology:
The freezing point method was used. No other information is given.
Sample Information:
- Lithium formate was prepared by dehydrating the monohydrate at 367.2 K.
Measurement Errors:
Ambient temperature: The temperature was controlled to within ±0.5 K.
System Components:
- Lithium formate, $\ce{ LiCHO2 }$; [556-63-8] NIST WebBook
- Formic acid, $\ce{ CH2O2 }$; [64-18-6] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $T$ (°C) | 100w1 | $100 x_{1}$ | Phase (s) () |
|---|---|---|---|---|
| 273.2 | 0 | 25.4 | 23.18a | LiCHO2 |
| 291.2 | 18 | 25.9 | 23.65a | LiCHO2 |
| 312.2 | 39 | 26.4 | 24.12a | LiCHO2 |
| 333.2 | 60 | 26.9 | 24.59a | LiCHO2 |
| 352.2 | 79 | 27.8 | 25.44a | LiCHO2 |
(a) These values were calculated by the compiler.
