SDS Volume
Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 18
Source Publication
Yalkowsky, S. H.; Orr, R. J.; Valvani, S. C.; Ind. Eng. Chem. Fundam. 1979, 18(4), 351-3.
Conditions:
Room Temp: 25 °C
Compiler:
Methodology:
A small excess of solute in water was agitated for a period of 4-48 hours (the exact time for equilibration was not reported in single cases) and then filtered. The saturated solution was extracted with a small volume of methylene chloride which was then assayed spectrophotometrically. At lease two independent determinations were carried out.
Sample Information:
- Commercial product (Aldrich or Eastman), used as received.
- Source and purity not specified.
Measurement Errors:
Ambient temperature: ±1 K (authors).
Mass concentration (m/v) (1): ±10% (authors).
System Components:
- 1,2,3,4-Tetrachlorobenzene, $\ce{ C6H2Cl4 }$; [634-66-2] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $C_{1}$ (mol/dm3) b | $x_{1}$ a | Cm1 ($\pu{g(\rm{1})/dm3}$) a |
|---|---|---|---|
| 25 | 2.0 x 10-5 | 3.61 x 10-7 | 4.32 x 10-3 |
(a) Calculated by F. W. Getzen.
(b) Reported.
