Compilation - Toluene with Water (IUPAC SDS Volume 37)
SDS Volume (457)
Volume 37. Hydrocarbons in Water and Seawater, Part I, p 397
Original Measurements
Variables:
Room Temp: 0 - 50 °C
Prepared by:
Method/Apparatus/Procedure:
Component (1) was introduced into a thermostatted flask and saturated for 5 hrs. with (2). Next, calcium hydride was added and the evolving hydrogen volume measured and hence the concentration of (2) in (1) was evaluated.
Source and Purity of Materials:
- Not specified.
- not specified.
Estimated Errors:
Ambient temperature: Not specified.
Components:
- Toluene, $\ce{ C7H8 }$; [108-88-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Solubility of water in toluene
| $T$ (°C) | MR2 (g1/100 g2) | $x_{2}$ |
|---|---|---|
| 0 | 0.02704 | 1.382 x 10-3 |
| 10 | 0.0316 | 1.61 x 10-3 |
| 20 | 0.0460 | 2.35 x 10-3 |
| 30 | 0.0615 | 3.14 x 10-3 |
| 40 | 0.0750 | 3.82 x 10-3 |
| 50 | 0.0965 | 4.92 x 10-3 |


