SDS Volume (4553)

Volume 72. Nitromethane with Water or Organic Solvents: Ternary and Quaternary Systems, p None

Original Measurements

Malesinska, B.; Malesinski, W.; Bull. Acad. Pol. Sci.: Ser. Sci. Chim. 11, 475 (1963).

Variables:

Temperature: 372 - 396 K

Prepared by:

V.P. Sazonov

Method/Apparatus/Procedure:

No experimental details given.

Source and Purity of Materials:
  1. Source not specified; purity not specified.
  2. Source not specified; purity not specified.
  3. Source not specified; purity not specified.
Experimental Data

Nitromethane with Alkanes (C7-C13) and Water

Components:

(1) Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
(2) Heptane, $\ce{ C7H16 }$; [142-82-5] NIST WebBook
(2) Octane, $\ce{ C8H18 }$; [111-65-9] NIST WebBook
(2) Decane, $\ce{ C10H22 }$; [124-18-5] NIST WebBook
(2) Undecane, $\ce{ C11H24 }$; [1120-21-4] NIST WebBook
(2) Dodecane, $\ce{ C12H26 }$; [112-40-3] NIST WebBook
(2) Tridecane, $\ce{ C13H28 }$; [629-50-5] NIST WebBook
(3) Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook

Experimental Values:
Maximal temperature of transition from the three- to the two-phase system in ternary nitromethane + alkane + water
T (°C)T (K)
122.5 395.65
116.1 389.25
108.7 381.85
106.12 379.27
104.75 377.9
98.7 371.85

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