SDS Volume (4543)

Volume 72. Nitromethane with Water or Organic Solvents: Ternary and Quaternary Systems, p None

Original Measurements

Sazonov, V. P.; Chernysheva, M. F.; Zh. Fiz. Khim. 49, 2463 (1975).
Sazonov, V. P.; Chernysheva, M. F.; Zh. Obshch. Khim. 46, 997-1000 (1976).

Variables:

Room Temp: 293 - 439 $\pu{K}$

Prepared by:

N.V. Sazonov, V.P. Sazonov

Method/Apparatus/Procedure:

The synthetic method was used. Ampoules containing mixtures were suspended from a vertical roller linked to a shaking machine, which switched on at definite time intervals. Water bath temperature was controlled with a proportional temperature regulator and checked with mercury thermometers. Close to aphase transition, heating or cooling was effected at 0.03 °/h. Solubility temperature of the liquid phase was determined both with heating and cooling, and the average taken. The thermostat contained silicone oil above 80 °C.

Source and Purity of Materials:

1. Source not specified; pure grade reagent; dried and repeatedly distilled in a packed glass column; no impurities detectable by gas chromatography.
2. Source not specified; pure grade reagent; dried and repeatedly distilled at vacuum; 99.5 mole% purity.
3. Twice distilled.

Estimated Errors:

Ambient temperature: taking ±0.01 K (293 K to 323 K); ±0.05 K (323 K to 373 K) and ±0.2 K (above 373 K).