Compilation - Nitromethane with 2-Methyl-2-propanol and Water (IUPAC SDS Volume 72)

SDS Volume (4520)

Volume 72. Nitromethane with Water or Organic Solvents: Ternary and Quaternary Systems, p None

Original Measurements

Zhuravlev, E. F.; Maslovskaya, N. V.; Zh. Obshch. Khim. 44, 1849 (1974).

Variables:

Room Temp: 293 $\pu{K}$

Prepared by:

V.P. Sazonov

Method/Apparatus/Procedure:

The solubility curve was determined by the titration method. No details were reported.

Source and Purity of Materials:
  1. Source not specified, pure grade; distilled.
  2. Source not specified, pure grade; distilled.
  3. Doubly distilled.
Estimated Errors:

Ambient temperature: Not reported.

Components:
  1. Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
  2. 2-Methyl-2-propanol, $\ce{ C4H10O }$; [75-65-0] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data

Estimated plait point: w1 = 0.303, w2 = 0.278 (x1 = 0.155, x2 = 0.117, compiler).

Mutual solubility of nitromethane, 2-methyl-2-propanol and water
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
20.0293.2 0.09000.0000 0.02800.0000
20.0293.2 0.11910.1400 0.04340.0420
20.0293.2 0.16050.1945 0.06410.0639
20.0293.2 0.19230.2311 0.08230.0815
20.0293.2 0.22370.2544 0.10160.0952
20.0293.2 0.25860.2613 0.12310.1025
20.0293.2 0.27060.2644 0.13110.1055
20.0293.2 0.28420.2810 0.14290.1164
20.0293.2 0.35750.2849 0.19820.1301
20.0293.2 0.38730.2960 0.22730.1431
20.0293.2 0.42310.2950 0.26100.1499
20.0293.2 0.50580.2773 0.34430.1555
20.0293.2 0.55270.2650 0.39810.1572
20.0293.2 0.59980.2502 0.45650.1568
20.0293.2 0.65460.2298 0.52990.1532
20.0293.2 0.73090.1833 0.62340.1287
20.0293.2 0.82780.1220 0.75370.0915
20.0293.2 0.98000.0000 0.93500.0000

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