Nitromethane with Butanoic acid and Water (IUPAC SDS Volume 72)

SDS Volume

Volume 72. Nitromethane with Water or Organic Solvents: Ternary and Quaternary Systems, p 1486

Source Publication

Maslovskaya, N. V.; Dissertation, Kalinin University, 1974.

Conditions:

Room Temp: 293 and 313 $\pu{K}$

Compiler:

V.P. Sazonov

Methodology:

Two methods were used. The solubility curve was determined by the titration method. The analytical method was used, samples being withdrawn from coexisting liquid phases at equilibrium for analysis by refractometry.

Sample Information:
  1. Source not specified, pure grade reagent; distilled; BP = 101.0°C; $n_{D}^{20}$ = 1.3818, $d_{4}^{20}$ = 1.1385.
  2. Source not specified, dried and distilled; BP = 162.6°C; $n_{D}^{20}$ = 1.3995, $d_{4}^{20}$ = 0.9620.
  3. Doubly distilled.
Measurement Errors:

Ambient temperature: not reported.

System Components:
  1. Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
  2. Butanoic acid, $\ce{ C4H8O2 }$; [107-92-6] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
20.0293.2 0.9600.017 0.9130.011
20.0293.2 0.8300.112 0.7570.071
20.0293.2 0.6950.208 0.5950.123
20.0293.2 0.5250.310 0.4040.165
20.0293.2 0.4150.362 0.2920.176
20.0293.2 0.3760.374 0.2530.175
20.0293.2 0.8690.068 0.7690.042
20.0293.2 0.8060.112 0.6940.067
20.0293.2 0.6870.188 0.5540.105
20.0293.2 0.5180.260 0.3570.124
20.0293.2 0.3920.285 0.2530.128
20.0293.2 0.0916 x 10-3 0.0291 x 10-3
20.0293.2 0.1000.046 0.0330.011
20.0293.2 0.1030.060 0.0350.014
20.0293.2 0.1110.090 0.0390.022
20.0293.2 0.1170.110 0.0420.027
20.0293.2 0.1220.130 0.0440.033
20.0293.2 0.1140.032 0.0387 x 10-3
20.0293.2 0.1300.060 0.0450.014
20.0293.2 0.1360.075 0.0480.018
20.0293.2 0.1410.082 0.0500.020
20.0293.2 0.1470.090 0.0530.022

Download Data   link to XML output link to JSON output link to JSON-LD output