SDS Volume

Volume 72. Nitromethane with Water or Organic Solvents: Ternary and Quaternary Systems, p 1483

Source Publication

Schumacher, J. E.; Hunt, H.; Ind. Eng. Chem. 34, 701-4 (1942).

Conditions:

Room Temp: 298 $\pu{K}$

Compiler:

V.P. Sazonov

Methodology:

The method described by Fowler and Hunt [1] was used. No experimental details given.

Sample Information:
  1. Commercial Solvents Corp., technical grade; fractionated; BP = 101.0-101.7°C, $\rho^{25} = \pu{1129.0 g L-1}$.
  2. Carbide and Carbon Co., technical grade; dried and fractionated; BP = 82.0-82.3°C, $\rho^{25} = \pu{80.3 g L-1}$.
  3. Distilled.
Measurement Errors:

Ambient temperature: control to ±0.5 K.

Methodology Citation

1 Fowler, A. R.; Hunt, H.; Ind. Eng. Chem. 33, 90-5 (1941).

System Components:
  1. Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
  2. 2-Propanol, $\ce{ C3H8O }$; [67-63-0] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
25298 0.11030.000 0.03530.000
25298 0.1290.136 0.0470.050
25298 0.1950.216 0.0810.091
25298 0.2660.239 0.1220.111
25298 0.2680.241 0.1230.112
25298 0.3430.242 0.1720.123
25298 0.3420.242 0.1710.123
25298 0.4160.243 0.2290.136
25298 0.4170.243 0.2300.136
25298 0.5010.231 0.3050.143
25298 0.5900.214 0.4010.148
25298 0.7040.172 0.5420.135
25298 0.7780.132 0.6390.110
25298 0.97720.000 0.92680.000

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