Compilation - Nitromethane with 2-Propanol and Water (IUPAC SDS Volume 72)

SDS Volume (4512)

Volume 72. Nitromethane with Water or Organic Solvents: Ternary and Quaternary Systems, p None

Original Measurements

Schumacher, J. E.; Hunt, H.; Ind. Eng. Chem. 34, 701-4 (1942).

Variables:

Room Temp: 298 $\pu{K}$

Prepared by:

V.P. Sazonov

Method/Apparatus/Procedure:

The method described by Fowler and Hunt [1] was used. No experimental details given.

Source and Purity of Materials:
  1. Commercial Solvents Corp., technical grade; fractionated; BP = 101.0-101.7°C, $\rho^{25} = \pu{1129.0 g L-1}$.
  2. Carbide and Carbon Co., technical grade; dried and fractionated; BP = 82.0-82.3°C, $\rho^{25} = \pu{80.3 g L-1}$.
  3. Distilled.
Estimated Errors:

Ambient temperature: control to ±0.5 K.

References

1 Fowler, A. R.; Hunt, H.; Ind. Eng. Chem. 33, 90-5 (1941).

Components:
  1. Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
  2. 2-Propanol, $\ce{ C3H8O }$; [67-63-0] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Mutual solubility of nitromethane, 2-propanol and water
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
25298 0.11030.000 0.03530.000
25298 0.1290.136 0.0470.050
25298 0.1950.216 0.0810.091
25298 0.2660.239 0.1220.111
25298 0.2680.241 0.1230.112
25298 0.3430.242 0.1720.123
25298 0.3420.242 0.1710.123
25298 0.4160.243 0.2290.136
25298 0.4170.243 0.2300.136
25298 0.5010.231 0.3050.143
25298 0.5900.214 0.4010.148
25298 0.7040.172 0.5420.135
25298 0.7780.132 0.6390.110
25298 0.97720.000 0.92680.000

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