Nitromethane with Tetrachloroethene and Water (IUPAC SDS Volume 72)

SDS Volume

Volume 72. Nitromethane with Water or Organic Solvents: Ternary and Quaternary Systems, p 1468

Source Publication

Schuberth, H.; Kranke, P.; Z. Phys. Chem. 245O, 49-67 (1970).

Conditions:

Room Temp: 293 and 323 $\pu{K}$

Compiler:

V.P. Sazonov

Methodology:

The analytical method was used. Mixtures of (1), (2) and (3) were stirred at a given temperature for a time interval sufficient to achieve equilibrium between liquid phases. After this, the samples of the separate phases were selected for chromatographic analysis. Injections were made with a syringe kept at the corresponding temperature.

Sample Information:
  1. Source not specified, distilled; BP = 100.9°C; $n_{D}^{20}$ = 1.3819; $\rho^{20} = \pu{1138.0 g L-1}$.
  2. Source not specified, distilled; BP = 120.6°C; $n_{D}^{20}$ = 1.5055; $\rho^{20} = \pu{1622.9 g L-1}$.
  3. Distilled.
Measurement Errors:

Ambient temperature: Not reported.

System Components:
  1. Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
  2. Tetrachloroethene, $\ce{ C2Cl4 }$; [127-18-4] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) $T$ ($\pu{K}$) $x_{1}$ $x_{2}$
15.0288.2 0.8470.124
20.0293.2 0.8420.129
30.0303.2 0.8210.149
40.0313.2 0.7750.190
50.0323.2 0.7080.250
15.0288.2 0.0980.898
20.0293.2 0.1130.882
30.0303.2 0.1540.839
40.0313.2 0.2240.767
50.0323.2 0.3310.659
15.0288.2 0.029-
20.0293.2 0.030--
30.0303.2 0.032--
40.0313.2 0.035--
50.0323.2 0.039--
15.0288.2 0.7100.283
20.0293.2 0.7010.292
30.0303.2 0.6650.328
40.0313.2 0.5950.397
50.0323.2 0.5060.485
15.0288.2 0.0380.961
20.0293.2 0.0450.954
30.0303.2 0.0630.936
40.0313.2 0.0970.902
50.0323.2 0.1560.843
15.0288.2 0.092-
20.0293.2 0.095-
30.0303.2 0.101-
40.0313.2 0.109-
50.0323.2 0.121-

(a) The water-rich phase contained traces of tetrachloroethene.

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