Compilation - Nitromethane with 1-Nonanol and Naphthalene (IUPAC SDS Volume 72)

SDS Volume (4473)

Volume 72. Nitromethane with Water or Organic Solvents: Ternary and Quaternary Systems, p None

Original Measurements

Sazonov, V. P.; Chernysheva, M. F.; Zh. Obshch. Khim. 46, 219 (1976).
Chernysheva, M. F.; Ph.D. Dissertation, Novosibirsk Institute of Inorganic Chemistry, Russia, 1982.

Variables:

Room Temp: 291 - 322 $\pu{K}$

Prepared by:

N.V. Sazonov, V.P. Sazonov

Method/Apparatus/Procedure:

The synthetic method (Alekseev [1]) was used. Ampoules containing mixtures were suspended from a vertical roller linked to a shaking machine, which switched on at definite time intervals. Water bath temperature was controlled with a proportional temperature regulator and checked with mercury thermometers. Close to a phase transition, heating or cooling was effected at 0.03 °C/hr. Solubility temperature of the liquid phase was determined both with heating and cooling, and the average taken.

Source and Purity of Materials:
  1. Source not specified; pure grade reagent; dried and twice distilled on a packed column of 20 theoretical plates; no impurities detectable by gas chromatography.
  2. Source not specified, pure grade reagent; dried and distilled under vacuum; 99.5 mole% purity.
  3. Source not specified, analytical purity; purified by recrystallization; MP = 80.2°C.
Estimated Errors:

Ambient temperature: ±0.02 K for liquid phase and ±0.03 K for solid phase.

References

1 Alekseev, V. F.; Zh. Russ. Fiz. -Khim. O-va 8, 249 (1876).

Components:
  1. Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
  2. 1-Nonanol, $\ce{ C9H20O }$; [143-08-8] NIST WebBook
  3. Naphthalene, $\ce{ C10H8 }$; [91-20-3] NIST WebBook
Experimental Data

The temperatures of phase transitions were determined in ternary mixtures with a constant mass content of (3), respectively 25.0, 30.0, and 40 mass %, and also in ternary mixtures with a constant mass relationship of (1) and (2) as 20.0:80.0, 40.0:60.0, 55.0:45.0, 70.0:30.0, and 85.0:15.0, respectively. L1 nitromethane-rich phase; L2 alcohol-rich phase; S solid naphthalene. The phase which is being dissolved is indicated in the table.

Table 1. Temperatures of phase transition L1 +L2+ S ↔L + S
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
18.17291.32 0.67500.0750 0.81740.0384
21.09294.24 0.15000.6000 0.28680.4855
21.45294.60 0.63740.1126 0.79270.0592
22.83295.98 0.18750.5625 0.34430.4371
23.10296.25 0.60000.1500 0.76670.0812
23.84296.99 0.22500.5250 0.39740.3923
24.00297.15 0.56250.1875 0.73930.1042
24.39297.54 0.26250.4875 0.44650.3510
24.54297.69 0.52500.2250 0.71020.1287
24.73297.88 0.30000.4500 0.49220.3124
24.76297.91 0.48750.2625 0.67930.1548
24.84297.99 0.45000.3000 0.64650.1824
24.88298.03 0.41230.3377 0.61150.2119
24.88298.03 0.33780.4122 0.53510.2763
24.92298.07 0.37500.3750 0.57450.2431
21.14294.29 0.14020.5598 0.26960.4556
21.52294.77 0.59500.1050 0.76060.0568
22.74295.89 0.17520.5248 0.32440.4111
23.01296.16 0.56000.1400 0.73480.0777
23.88297.03 0.21000.4900 0.37490.3701
24.02297.17 0.52570.1743 0.70820.0993
24.44297.59 0.24490.4551 0.42200.3318
24.53297.68 0.49000.2100 0.67890.1232
24.73297.88 0.28000.4200 0.46620.2959
24.77297.92 0.45500.2450 0.64860.1478
24.88298.03 0.31500.3850 0.50740.2674
24.89298.04 0.42000.2800 0.61640.1739
24.91298.06 0.35000.3500 0.54610.2310
24.92298.07 0.38500.3150 0.58230.2016
20.86294.01 0.50990.0901 0.69040.0517
21.20294.35 0.12010.4799 0.23380.3953
22.83295.98 0.15030.4497 0.28300.3583
22.85296.00 0.48010.1199 0.66560.0703
23.81296.96 0.17990.4201 0.32820.3243
24.00297.15 0.45000.1500 0.63920.0902
24.41297.56 0.21010.3899 0.37150.2917
24.52297.67 0.42000.1800 0.61170.1109
24.68297.83 0.39000.2100 0.58270.1327
24.71297.86 0.24000.3600 0.41180.2613
24.83297.98 0.26990.3301 0.44980.2327
24.85298.00 0.36120.2388 0.55340.1548
24.85298.00 0.33010.2699 0.52000.1799
24.88298.03 0.30000.3000 0.48590.2056
21.30294.45 0.68290.1205 0.82520.0617
21.30294.45 0.66380.1172 0.81180.0606
21.30294.45 0.64690.1141 0.79960.0597
21.30294.45 0.62930.1111 0.78670.0587
24.52297.67 0.53160.2278 0.71590.1298
24.52297.67 0.51810.2220 0.70410.1277
24.90298.05 0.40690.3330 0.60580.2098
24.90298.05 0.39630.3242 0.59450.2058
24.70297.85 0.30420.4563 0.49760.3158
24.70297.85 0.29510.4426 0.48590.3084
21.12294.27 0.16000.6401 0.30420.5148
21.12294.27 0.15590.6237 0.29710.5029
21.10295.25 0.14800.5921 0.28340.4796

(a) Critical opalescence

Download Data   link to XML output link to JSON output link to JSON-LD output