Compilation - Nitromethane with Methanol and Water (IUPAC SDS Volume 72)

SDS Volume (4464)

Volume 72. Nitromethane with Water or Organic Solvents: Ternary and Quaternary Systems, p None

Original Measurements

Zhuravlev, E. F.; Maslovskaya, N. V.; Zh. Obshch. Khim. 44, 1849 (1974).

Variables:

Room Temp: 293 $\pu{K}$

Prepared by:

V.P. Sazonov

Method/Apparatus/Procedure:

The solubility curve was determined by the titration method. No further details were reported.

Source and Purity of Materials:
  1. Source not specified, pure grade; distilled.
  2. Source not specified, pure grade; distilled.
  3. Doubly distilled.
Estimated Errors:

Ambient temperature: Not reported.

Components:
  1. Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
  2. Methanol, $\ce{ CH4O }$; [67-56-1] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data

Estimated plait point: w1 = 0.521, w2 = 0.263 (x1 = 0.297, x2 = 0.286, compiler).

Mutual solubility of nitromethane, methanol and water
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
20.0293.2 0.09000.0000 0.02840.0000
20.0293.2 0.10000.0184 0.03200.0112
20.0293.2 0.10100.0522 0.03290.0324
20.0293.2 0.10700.1150 0.03610.0740
20.0293.2 0.11800.1826 0.04160.1227
20.0293.2 0.14050.2300 0.05180.1616
20.0293.2 0.18000.2960 0.07150.2239
20.0293.2 0.23200.3205 0.09840.2589
20.0293.2 0.30150.3297 0.13840.2883
20.0293.2 0.34070.3183 0.16210.2885
20.0293.2 0.38280.3034 0.18920.2856
20.0293.2 0.46780.2802 0.25220.2877
20.0293.2 0.55000.2450 0.32140.2728
20.0293.2 0.56850.2356 0.33820.2670
20.0293.2 0.62770.2148 0.39970.2606
20.0293.2 0.68420.1883 0.46390.2432
20.0293.2 0.78140.1310 0.58850.1880
20.0293.2 0.80890.1211 0.63360.1807
20.0293.2 0.98000.0000 0.93530.0000

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