SDS Volume

Volume 72. Nitromethane with Water or Organic Solvents: Ternary and Quaternary Systems, p 1601

Source Publication

Suri, S. K.; Talanta 17, 577 (1970).

Conditions:

Room Temp: 313 $\pu{K}$

Compiler:

V.P. Sazonov

Methodology:

The titration method, as described in Dunnery and Atwood [2], was used. Solutions and solvents were thermally equilibrated and held at constant temperature during titrations. Enough solution was taken to give a titer of 10 to 20 mL.

Sample Information:
  1. Source not specified; purified by methods as in Weissberger [1]; $\rho^{30} = \pu{1125.0 g L-1}$; $\rho^{40} = \pu{1110.8 g L-1}$.
  2. Source not specified; purified by methods as in Weissberger [1]; $\rho^{30} = \pu{868.5 g L-1}$, $\rho^{40} = \pu{857.5 g L-1}$.
  3. Source not specified; purified by methods as in Weissberger [1]; $\rho^{30} = \pu{769.4 g L-1}$. $\rho^{40} = \pu{759.6 g L-1}$.
Measurement Errors:

Ambient temperature: control to ±0.1 K.

Methodology Citations

1 Weissberger, A.; Technique of Organic Chemistry. Interscience, New York, 1959.
2 Dunnery, D. A.; Atwood, G. R.; Talanta 15, 855 (1968).

System Components:
  1. Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
  2. Benzene, $\ce{ C6H6 }$; [71-43-2] NIST WebBook
  3. Cyclohexane, $\ce{ C6H12 }$; [110-82-7] NIST WebBook
Experimental Data
$T$ (°C) $T$ ($\pu{K}$) w1 w2 $x_{1}$ $x_{2}$
40.0313.2 0.0510.015 0.0690.016
40.0313.2 0.0730.089 0.0970.093
40.0313.2 0.1540.193 0.1980.194
40.0313.2 0.1820.222 0.2310.220
40.0313.2 0.2520.241 0.3120.233
40.0313.2 0.3410.238 0.4100.223
40.0313.2 0.4210.229 0.4930.210
40.0313.2 0.5390.211 0.6090.186
40.0313.2 0.6250.182 0.6890.157
40.0313.2 0.6920.154 0.7490.130
40.0313.2 0.7780.106 0.8230.088
40.0313.2 0.8530.055 0.8860.045

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