NIST-IUPAC Solubility Data Series

Compilation - Nitromethane with 2,2’-Iminobisethanol and 1-Hexadecanol (IUPAC SDS Volume 72)

SDS Volume (4449)

Volume 72. Nitromethane with Water or Organic Solvents: Ternary and Quaternary Systems, p None

Original Measurements

Zhuravleva, I. K.; Zhuravlev, E. F.; Sukhova, I. A.; Khisametdinova, Z. Z.; Zh. Fiz. Khim. 50, 405-10 (1976).

Variables:

Room Temp: 323 - 353 $\pu{K}$

Prepared by:

V.P. Sazonov

Method/Apparatus/Procedure:

The solubility temperatures of the liquid phases were determined by the synthetic method (Alekseev [1]). No experimental details given.

Source and Purity of Materials:

Source not specified; freshly distilled.
Source not specified, freshly distilled.
Source not specified, freshly distilled.

Estimated Errors:

Ambient temperature: Not specified.

References

¹ Alekseev, V. F.; Zh. Russ. Fiz. -Khim. O-va 8, 249 (1876).

Components:

Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
2,2'-Iminobisethanol, $\ce{ C4H11NO2 }$; [111-42-2] NIST WebBook
1-Hexadecanol, $\ce{ C16H34O }$; [1454-85-9] NIST WebBook

Experimental Data

The solubility temperatures of the liquid phases were determined in ternary mixtures with a constant mass relationship of (2) and (3) 10.0:90.0, 20.0:80.0, 30.0:70.0, 40.0:60.0, 50.0:50.0, 60.0:40.0, 70.0:30.0, 80.0:20.0, and 90.0:10.0, respectively. These data were also reported in graphical form as isothermal curves ternary system solubility.

Solubility of nitromethane, 2,2'-iminobisethanol and 1-hexadecanol*

$T$ (°C)	$T$ ($\pu{K}$)	w₁	w₂	$x_{1}$	$x_{2}$
50	323	0.102	0.000	0.311	0.000
50	323	0.131	0.087	0.346	0.134
50	323	0.165	0.167	0.384	0.225
50	323	0.200	0.240	0.416	0.290
50	323	0.238	0.305	0.449	0.334
50	323	0.290	0.355	0.495	0.352
50	323	0.293	0.424	0.480	0.403
50	323	0.340	0.462	0.517	0.408
50	323	0.418	0.466	0.582	0.377
50	323	0.454	0.491	0.603	0.379
50	323	0.379	0.621	0.513	0.487
50	323	0.105	0.268	0.251	0.372
50	323	0.187	0.325	0.375	0.379
50	323	0.234	0.383	0.423	0.402
50	323	0.271	0.437	0.453	0.424
50	323	0.304	0.487	0.476	0.442
50	323	0.322	0.542	0.480	0.469
50	323	0.295	0.635	0.433	0.541
50	323	0.972	0.000	0.993	0.000
50	323	0.958	0.013	0.985	8 x 10^-3
50	323	0.950	0.020	0.980	0.012
50	323	0.942	0.029	0.975	0.017
50	323	0.929	0.043	0.967	0.026
50	323	0.890	0.077	0.944	0.047
50	323	0.874	0.101	0.931	0.062
50	323	0.894	0.095	0.939	0.058
50	323	0.928	0.072	0.957	0.043
60	333	0.156	0.000	0.423	0.000
60	333	0.188	0.081	0.449	0.112
60	333	0.231	0.154	0.486	0.188
60	333	0.277	0.217	0.522	0.238
60	333	0.321	0.272	0.552	0.272
60	333	0.422	0.289	0.637	0.253
60	333	0.461	0.323	0.656	0.267
60	333	0.483	0.362	0.660	0.287
60	333	0.614	0.309	0.755	0.221
60	333	0.710	0.232	0.826	0.157
60	333	0.864	0.136	0.916	0.084
60	333	0.892	0.054	0.952	0.034
60	333	0.918	0.033	0.967	0.020
60	333	0.932	0.020	0.975	0.012
60	333	0.949	0.010	0.983	6 x 10^-3
60	333	0.961	0.000	0.990	0.000
60	333	0.088	0.274	0.216	0.390
60	333	0.166	0.334	0.342	0.399
60	333	0.208	0.396	0.387	0.428
60	333	0.241	0.455	0.414	0.454
60	333	0.267	0.513	0.431	0.480
60	333	0.280	0.576	0.430	0.514
60	333	0.252	0.673	0.381	0.591
60	333	0.611	0.350	0.741	0.247
60	333	0.818	0.164	0.891	0.104
70	343	0.231	0.000	0.544	0.000
70	343	0.266	0.073	0.560	0.089
70	343	0.328	0.134	0.606	0.144
70	343	0.430	0.171	0.683	0.158
70	343	0.532	0.187	0.748	0.153
70	343	0.610	0.195	0.790	0.147
70	343	0.636	0.218	0.796	0.158
70	343	0.695	0.213	0.825	0.147
70	343	0.800	0.120	0.899	0.078
70	343	0.846	0.077	0.930	0.049
70	343	0.878	0.049	0.949	0.031
70	343	0.897	0.034	0.960	0.021
70	343	0.913	0.017	0.971	0.010
70	343	0.921	8 x 10^-3	0.976	5 x 10^-3
70	343	0.930	0.000	0.981	0.000
70	343	0.067	0.280	0.170	0.413
70	343	0.143	0.343	0.303	0.422
70	343	0.186	0.407	0.355	0.450
70	343	0.218	0.469	0.383	0.479
70	343	0.238	0.533	0.393	0.511
70	343	0.245	0.604	0.387	0.553
70	343	0.219	0.703	0.339	0.631
80	353	0.231	0.000	0.544	0.000
80	353	0.492	0.051	0.773	0.046
80	353	0.606	0.079	0.829	0.063
80	353	0.756	0.073	0.899	0.050
80	353	0.856	0.029	0.949	0.019
80	353	0.877	0.012	0.962	8 x 10^-3
80	353	0.899	0.000	0.973	0.000
80	353	0.038	0.289	0.101	0.447
80	353	0.125	0.350	0.272	0.441
80	353	0.166	0.417	0.323	0.472
80	353	0.191	0.485	0.345	0.508
80	353	0.210	0.553	0.355	0.544
80	353	0.216	0.627	0.349	0.588
80	353	0.186	0.733	0.294	0.673

(*) This table was prepared by the compiler from the published curves of ternary system solubility.

IUPAC-NIST Solubility Data Series, SRD 106