SDS Volume

Volume 71. Nitromethane with Water or Organic Solvents, p None

Source Publication

Clever, H. L.; Pirkle Jr., Q. R.; Allen Jr., B. J.; Derrick, M. E.; J. Chem. Eng. Data 17, 31-4 (1972).

Conditions:

Room Temp: 208 - 242 $\pu{K}$

Compiler:

V.P. Sazonov

Methodology:

The synthetic method was used. Solutions of (1) and (2) were sealed in 5 mL glass vials. Cloud points were observed visually in an acetone bath slowly cooled by addition of dry ice. Temperatures were taken on an alcohol thermometer.

Sample Information:
  1. Fisher; reagent grade; distilled at 60°C at 24.4 kPa.
  2. Phillips; research grade; purity 99.89 mole%.
Measurement Errors:

Ambient temperature: ±3 K.

System Components:
  1. Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
  2. 1,2,4-Trimethylbenzene, $\ce{ C9H12 }$; [95-63-6] NIST WebBook
Experimental Data
$T$ (°C) $T$ ($\pu{K}$) $x_{1}$ 100w1 a
-65208 0.25 14.5
-65208 - -
-60213 0.33 20.0
-60213 - -
-44229 0.44 28.5
-44229 - -
-40233 - -
-40233 0.88 78.8
-33240 0.66 49.6
-33240 - -
-31242 0.74 59.1
-31242 - -
-31242 - -
-31243 - -

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