SDS Volume
Volume 71. Nitromethane with Water or Organic Solvents, p None
Source Publication
Sazonov, V. P.; Zh. Obshch. Khim. 59, 2431-5 (1989).
Conditions:
Room Temp: 313 and 382 $\pu{K}$
Compilers:
Methodology:
The synthetic method was used. The apparatus with visual indication of turbidity was described by Sazonov, et al. [1]. No additional details were reported.
Sample Information:
- Source not specified; pure grade reagent; fractionally distilled; 99.85 mass% purity; $n_{D}^{20}$ = 1.3819, $\rho^{20} = \pu{1138.0 g L-1}$.
- Source not specified; reagent for chromatography; $n_{D}^{20}$ = 1.3877, $\rho^{20} = \pu{683.7 g L-1}$.
Measurement Errors:
Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
Pressure: Not reported.
Methodology Citation
1 Sazonov, V. P.; Chernysheva, M. F.; Zh. Obshch. Khim. 57, 46-54 (1987).
System Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- Heptane, $\ce{ C7H16 }$; [142-82-5] NIST WebBook
Experimental Data
| $T$ (°C) | $T$ ($\pu{K}$) | w1 | $x_{1}$ |
|---|---|---|---|
| 40.1 | 313.3 | - | - |
| 40.1 | 313.3 | 95.0 | 0.969 |
| 45.0 | 318.2 | 5.0 | 0.080 |
| 45.0 | 318.2 | - | - |
| 69.6 | 342.8 | 10.0 | 0.154 |
| 69.6 | 342.8 | - | - |
| 74.0 | 347.2 | - | - |
| 74.0 | 347.2 | 90.0 | 0.937 |
| 84.0 | 357.2 | 14.0 | 0.211 |
| 84.0 | 357.2 | - | - |
| 88.9 | 362.1 | - | - |
| 88.9 | 362.1 | 85.0 | 0.903 |
| 92.3 | 365.5 | 20.0 | 0.291 |
| 92.3 | 365.5 | - | - |
| 97.1 | 370.3 | - | - |
| 97.1 | 370.3 | 80.0 | 0.868 |
| 97.3 | 370.5 | 24.0 | 0.341 |
| 97.3 | 370.5 | - | - |
| 100.4 | 373.6 | - | - |
| 100.4 | 373.6 | 75.0 | 0.831 |
| 103.5 | 376.7 | 30.0 | 0.413 |
| 103.5 | 376.7 | - | - |
| 104.0 | 377.2 | - | - |
| 104.0 | 377.2 | 70.0 | 0.793 |
| 105.2 | 378.4 | 35.0 | 0.469 |
| 105.2 | 378.4 | - | - |
| 106.6 | 379.8 | 40.0 | 0.522 |
| 106.6 | 379.8 | - | - |
| 107.0 | 380.2 | - | - |
| 107.0 | 380.2 | 62.0 | 0.728 |
| 107.6 | 380.8 | 45.0 | 0.573 |
| 107.6 | 380.8 | - | - |
| 107.8 | 381.0 | 50.0 | 0.621 |
| 107.8 | 381.0 | - | - |
| 108.0 | 381.2 | 52.5 | 0.645 |
| 108.0 | 381.2 | 57.5 | 0.689 |
| 108.3 | 381.5 | - | - |
| 108.3 | 381.5 | 55.0 | 0.667 |
| 108.3 | 381.5 | 52.8 | 0.647 |
| 108.3 | 381.5 | 52.8 | UCST |


