Compilation - Nitromethane with Heptane (IUPAC SDS Volume 71)
SDS Volume (4392)
Volume 71. Nitromethane with Water or Organic Solvents, p 1220
Original Measurements
Kimura, C.; Kashiwaya, K.; Asahara, T.; Kogyo Kagaku Zasshi 59, 1126 (1956).
Variables:
Temperature: 303 K
Prepared by:
Method/Apparatus/Procedure:
The titration method was used. No further experimental details were given.
Source and Purity of Materials:
- Synthesized in the laboratory; purity not specified; b. p. = 101°C, n(20°C, D) = 1.3817, d(20°C) = 1137.2 g L-1.
- Source not specified; commercial material; purity not specified; b. p. = 98°C, n(20°C, D) = 1.3878, d(20°C)
d(20°C) = 683.2 g L-1.
Nitromethane with Heptane
Components:
(1) Nitromethane,
$\ce{ CH3NO2 }$;
[75-52-5]
NIST WebBook
(2) Heptane,
$\ce{ C7H16 }$;
[142-82-5]
NIST WebBook
Experimental Values:
The solubility of nitromethane in the (2)-rich phase at equilibrium at 30°C (303 K, compiler) was reported to be 100 w1 = 3.5. The corresponding mole fraction, x1, calculated by the compiler is 0.056.
The solubility of nitromethane in the (1)-rich phase at equilibrium at 30°C (303 K, compiler) was reported to be 100 w1 = 97.3. The corresponding mole fraction solubility, x1, calculated by the compiler is 0.983.
