SDS Volume
Volume 71. Nitromethane with Water or Organic Solvents, p None
Source Publication
Kimura, C.; Kashiwaya, K.; Asahara, T.; Kogyo Kagaku Zasshi 59, 1126 (1956).
Conditions:
Room Temp: 303 $\pu{K}$
Compiler:
Methodology:
The titration method was used. No further experimental details were given.
Sample Information:
- Synthesized in the laboratory; purity not specified; BP = 101°C, $n_{D}^{20}$ = 1.3817, $\rho^{20} = \pu{1137.2 g L-1}$.
- Source not specified; commercial material; purity not specified; BP = 98°C, $n_{D}^{20}$ = 1.3878, $\rho^{20} = \pu{683.2 g L-1}$.
Measurement Errors:
Ambient temperature: Not reported.
Mass concentration (m/v) (1): Not reported.
Pressure: Not reported.
System Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- Heptane, $\ce{ C7H16 }$; [142-82-5] NIST WebBook
Experimental Data
The solubility of nitromethane in the (2)-rich phase at equilibrium at 30°C (303 K, compiler) was reported to be 100 w1 = 3.5. The corresponding mole fraction, x1, calculated by the compiler is 0.056.
The solubility of nitromethane in the (1)-rich phase at equilibrium at 30°C (303 K, compiler) was reported to be 100 w1 = 97.3. The corresponding mole fraction solubility, x1, calculated by the compiler is 0.983.
