Compilation - Nitromethane with Hexane (IUPAC SDS Volume 71)
SDS Volume (4376)
Volume 71. Nitromethane with Water or Organic Solvents, p None
Original Measurements
Rolla, M.; Franzosini, P.; Riccardi, R. L.; Bottelli, L.; Z. Naturforsch. A 22, 48-53 (1967).
Variables:
Room Temp: 358 - 375 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The synthetic method, described by Franzosini, [1] was employed. No further details were reported.
Source and Purity of Materials:
- Carlo Erba; RP; distilled through a tube filled with $\ce{P2O5}$; FP = -29.15°C.
- Fluka AG; purist grade; purification as above.
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Pressure: Not specified.
References
Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- Hexane, $\ce{ C6H14 }$; [110-54-3] NIST WebBook
Experimental Data
Mutual solubility of nitromethane and hexane
| $T$ (°C) | $T$ ($\pu{K}$) | $x_{1}$ | 100w1 |
|---|---|---|---|
| 84.5 | 357.7 | 0.211 | 15.9 |
| 84.5 | 357.7 | - | - |
| 91.6 | 364.8 | - | - |
| 91.6 | 364.8 | 0.849 | 79.9 |
| 95.0 | 368.2 | - | - |
| 95.0 | 368.2 | 0.820 | 76.3 |
| 95.4 | 368.6 | 0.315 | 24.6 |
| 95.4 | 368.6 | - | - |
| 98.6 | 371.8 | 0.379 | 30.2 |
| 98.6 | 371.8 | - | - |
| 101.1 | 374.3 | - | - |
| 101.1 | 374.3 | 0.727 | 65.4 |
| 101.4 | 374.6 | 0.488 | 40.3 |
| 101.4 | 374.6 | - | - |
| 101.6 | 374.8 | 0.490 | 40.5 |
| 101.6 | 374.8 | - | - |
| 101.6 | 374.8 | 0.493 | 40.8 |
| 101.6 | 374.8 | - | - |
| 101.7 | 374.9 | - | - |
| 101.7 | 374.9 | 0.697 | 62.0 |
| 102.2 | 375.4 | 0.571 | 48.5 |
| 102.2 | 375.4 | 0.592 | 50.7 |
| 102.2 | 375.4 | 0.585 | 50.0 |
| 102.2 | 375.4 | 0.585 | UCST |
