Compilation - Nitromethane with 3-Methylpentane (IUPAC SDS Volume 71)
SDS Volume (4372)
Volume 71. Nitromethane with Water or Organic Solvents, p None
Original Measurements
Rolla, M.; Franzosini, P.; Riccardi, R. L.; Bottelli, L.; Z. Naturforsch. A 22, 48-53 (1967).
Variables:
Room Temp: 349 - 372 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The synthetic method, described by Franzosini, [1] was employed. No further details were reported.
Source and Purity of Materials:
- Carlo Erba; RP; distilled through a tube filled with $\ce{P2O5}$; FP = -29.15°C.
- Fluka AG; purist grade; purification as above.
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Pressure: Not specified.
References
Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- 3-Methylpentane, $\ce{ C6H14 }$; [96-14-0] NIST WebBook
Experimental Data
Mutual solubility of nitromethane and 3-methylpentane
| $T$ (°C) | $T$ ($\pu{K}$) | $x_{1}$ | 100w1 |
|---|---|---|---|
| 75.7 | 348.9 | 0.178 | 13.3 |
| 75.7 | 348.9 | - | - |
| 77.1 | 350.3 | - | - |
| 77.1 | 350.3 | 0.872 | 82.8 |
| 91.9 | 365.1 | - | - |
| 91.9 | 365.1 | 0.802 | 74.2 |
| 92.2 | 365.4 | 0.320 | 25.0 |
| 92.2 | 365.4 | - | - |
| 93.3 | 366.5 | 0.328 | 25.7 |
| 93.3 | 366.5 | - | - |
| 93.7 | 366.9 | 0.348 | 27.4 |
| 93.7 | 366.9 | - | - |
| 94.0 | 367.2 | - | - |
| 94.0 | 367.2 | 0.785 | 72.1 |
| 96.5 | 369.7 | - | - |
| 96.5 | 369.7 | 0.745 | 67.4 |
| 97.9 | 371.1 | 0.478 | 39.3 |
| 97.9 | 371.1 | - | - |
| 98.5 | 371.6 | 0.541 | 45.5 |
| 98.5 | 371.6 | 0.639 | 55.6 |
| 98.6 | 371.8 | 0.585 | 50.0 |
| 98.6 | 371.8 | 0.585 | UCST |
