SDS Volume (4370)
Volume 71. Nitromethane with Water or Organic Solvents, p None
Original Measurements
Rolla, M.; Franzosini, P.; Riccardi, R. L.; Bottelli, L.; Z. Naturforsch. A 22, 48-53 (1967).
Variables:
Room Temp: 345 - 370 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The synthetic method, described by Franzosini, [1] was employed. No further details were reported.
Source and Purity of Materials:
- Carlo Erba; RP; distilled through a tube filled with $\ce{P2O5}$; FP = -29.15°C.
- Fluka AG; purist grade; purification as above.
Estimated Errors:
Ambient temperature: Not specified.
Mass concentration (m/v) (1): Not specified.
Pressure: Not specified.
References
Components:
- Nitromethane, $\ce{ CH3NO2 }$; [75-52-5] NIST WebBook
- 2,3-Dimethylbutane, $\ce{ C6H14 }$; [79-29-8] NIST WebBook
Experimental Data
Mutual solubility of nitromethane and 2,3-dimethylbutane
| $T$ (°C) | $T$ ($\pu{K}$) | $x_{1}$ | w1 |
|---|---|---|---|
| 71.4 | 344.6 | - | - |
| 71.4 | 344.6 | 0.892 | 85.4 |
| 78.7 | 351.9 | - | - |
| 78.7 | 351.9 | 0.863 | 81.7 |
| 85.4 | 358.6 | 0.255 | 19.5 |
| 85.4 | 358.6 | - | - |
| 87.4 | 360.0 | 0.282 | 21.8 |
| 87.4 | 360.0 | - | - |
| 88.6 | 361.8 | 0.296 | 22.9 |
| 88.6 | 361.8 | - | - |
| 91.3 | 364.5 | 0.345 | 27.2 |
| 91.3 | 364.5 | - | - |
| 91.8 | 365.0 | - | - |
| 91.8 | 365.0 | 0.773 | 70.7 |
| 93.2 | 366.4 | - | - |
| 93.2 | 366.4 | 0.759 | 69.0 |
| 93.9 | 367.1 | 0.403 | 32.3 |
| 93.9 | 367.1 | - | - |
| 95.4 | 368.6 | 0.469 | 38.5 |
| 95.4 | 368.6 | - | - |
| 95.5 | 368.7 | 0.461 | 37.7 |
| 95.5 | 368.7 | - | - |
| 96.1 | 369.3 | 0.523 | 43.7 |
| 96.1 | 369.3 | 0.643 | 56.1 |
| 96.2 | 369.4 | 0.585 | 50.0 |
| 96.2 | 369.4 | 0.585 | UCST |
